Complex Carbohydrates (College Board AP Biology)

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Molecular Structure of Complex Carbohydrates

Carbohydrates

  • Carbohydrates are monomers of sugars
  • Monosaccharidescan join together via dehydration synthesis reactions to form disaccharides
  • A dehydration synthesis reaction is one in which 2 molecules join together via the formation of a new chemical bond, with a molecule of water being released in the process
  • A new covalent bond forms between the 2 monosaccharides, holding the disaccharide together
  • To calculate the chemical formula of a disaccharide, you add all the carbons, hydrogens and oxygens in both monomers then subtract 2 H and 1 O (for the water molecule lost)
  • All carbohydrates have the generic formula (CH2O)n
  • They derive their name from 'hydrates of carbon'

Diagram of the Formation of a Disaccharide from Two Monosaccharides

Carbohydrate synthesis showing the removal of one water molecule

Two monosaccharide monomers join together by dehydration synthesis to form a disaccharide

Uses of Carbohydrates

  • Carbohydrates have different functions in biology
    • Energy storage
      • Starch in plants
      • Glycogen in animals
    • Starch forms a large part of the energy intake in the diet of herbivores
  • Structural uses
    • Cellulose in plant cell walls
    • Chitin in some animals eg, insects
      • Forms an exoskeleton
  • Dietary fiber
    • Many structural carbohydrates (eg. cellulose) are largely indigestible and form a large part of the dietary fiber requirements in the animal diet
  • The types of monomer and the nature of the covalent bonds between monomers give each carbohydrate different properties
  • Some carbohydrates are formed from straight chains of monomers eg. amylose
  • Other carbohydrates are highly branched e.g glycogen
    • Highly branched carbohydrates have more terminal monomers (at the ends of a chain)
    • This makes them quicker to be synthesized and broken down
    • Which is an advantage for an energy storage compound that needs to be built up/used quickly

Exam Tip

Remember, you don't need to know the precise structures of the various monosaccharides and other carbohydrates. However, you should recognize that structure determines function and that you may see an AP question that presents different carbohydrate structures and asks you to determine their most likely functions. 

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Phil

Author: Phil

Phil has a BSc in Biochemistry from the University of Birmingham, followed by an MBA from Manchester Business School. He has 15 years of teaching and tutoring experience, teaching Biology in schools before becoming director of a growing tuition agency. He has also examined Biology for one of the leading UK exam boards. Phil has a particular passion for empowering students to overcome their fear of numbers in a scientific context.