Exponential Decay (AQA A Level Physics): Revision Note
Exam code: 7408
Exponential decay
In radioactive decay, the number of undecayed nuclei falls very rapidly, without ever reaching zero
Such a model is known as exponential decay
The graph of number of undecayed nuclei against time has a very distinctive shape:

The key features of this graph are:
The steeper the slope, the larger the decay constant
(and vice versa)
The decay curves always start on the y-axis at the initial number of undecayed nuclei (
)
Equations for radioactive decay
The number of undecayed nuclei N can be represented in exponential form by the equation:
Where:
= the initial number of undecayed nuclei (when
)
= number of undecayed nuclei at a certain time
= decay constant (s-1)
= time interval (s)
The number of nuclei can be substituted for other quantities
For example, the activity
is directly proportional to
, so it can also be represented in exponential form by the equation:
Where:
= activity at a certain time
(Bq)
= initial activity (Bq)
The received count rate
is related to the activity of the sample, hence it can also be represented in exponential form by the equation:
Where:
= count rate at a certain time
(counts per minute or cpm)
= initial count rate (counts per minute or cpm)
The exponential function e
The symbol
represents the exponential constant
It is approximately equal to
= 2.718
On a calculator it is shown by the button
The inverse function of
is
, known as the natural logarithmic function
This is because, if
, then
Worked Example
Strontium-90 decays with the emission of a -particle to form yttrium-90.
The decay constant of strontium-90 is 0.025 year -1.
Determine the activity of the sample after 5.0 years, expressing the answer as a fraction of the initial activity
.
[2]
Answer:
Step 1: Write out the known quantities
Decay constant,
Time interval,
Both quantities have the same unit, so there is no need for conversion
Step 2: Write the equation for activity in exponential form
Step 3: Rearrange the equation for the ratio between and
Step 4: Calculate the ratio
[1 mark]
[1 mark]
Therefore, the activity of strontium-90 decreases by a factor of 0.88, or 12%, after 5 years
Using molar mass & the Avogadro constant
Molar mass
The molar mass, or molecular mass, of a substance is the mass of a substance, in grams, in one mole
Its unit is g mol-1
The number of moles from this can be calculated using the equation:
Avogadro’s constant
Avogadro’s constant
is defined as:
The number of atoms in one mole of a substance; equal to 6.02 × 1023 mol-1
For example, 1 mole of sodium (Na) contains 6.02 × 1023 atoms of sodium
The number of atoms, or nuclei, can be determined using the equation:
Worked Example
Americium-241 is an artificially produced radioactive element that emits α-particles.
In a smoke detector, a sample of americium-241 of mass 5.1 µg is found to have an activity of 5.9 × 105 Bq. The supplier’s website says the americium-241 in their smoke detectors initially has an activity level of 6.1 × 105 Bq.
Determine:
(a) the number of nuclei in the sample of americium-241 [2]
(b) the decay constant of americium-241 [2]
(c) the age of the smoke detector in years [3]
Answer:
Part (a)
Step 1: Write down the known quantities
Molecular mass of americium = 241
Avogadro constant,
Step 2: Write down the equation relating number of nuclei, mass and molecular mass
Step 3: Calculate the number of nuclei
[1 mark]
[1 mark]
Part (b)
Step 1: Write down the known quantities
Activity,
Number of nuclei,
Step 2: Write the equation for activity
Activity:
Step 3: Rearrange for decay constant λ and calculate the answer
[1 mark]
[1 mark]
Part (c)
Step 1: Write down the known quantities
Activity,
Initial activity,
Decay constant,
Step 2: Write the equation for activity in exponential form
Step 3: Rearrange for time t
[1 mark]
Step 4: Calculate the age of the smoke detector and convert to years
[1 mark]
[1 mark]
Therefore, the smoke detector is 22.8 years old
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