Exponential Decay (AQA A Level Physics): Revision Note

Exam code: 7408

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Exponential decay

  • In radioactive decay, the number of undecayed nuclei falls very rapidly, without ever reaching zero

    • Such a model is known as exponential decay

  • The graph of number of undecayed nuclei against time has a very distinctive shape:

Three exponential decay curves of undecayed nuclei against time, all starting at N0 and falling at different rates. Steeper curves have larger decay constant lambda, while the shallowest has a smaller lambda.
Radioactive decay follows an exponential pattern. The graph shows three different isotopes each with a different rate of decay
  • The key features of this graph are:

    • The steeper the slope, the larger the decay constant lambda (and vice versa)

    • The decay curves always start on the y-axis at the initial number of undecayed nuclei (N subscript 0)

Equations for radioactive decay

  • The number of undecayed nuclei N can be represented in exponential form by the equation:

N space equals space N subscript 0 space e to the power of negative lambda t end exponent

  • Where:

    • N subscript 0 = the initial number of undecayed nuclei (when t space equals space 0)

    • N = number of undecayed nuclei at a certain time t

    • lambda = decay constant (s-1)

    • t = time interval (s)

  • The number of nuclei can be substituted for other quantities

  • For example, the activity A is directly proportional to N, so it can also be represented in exponential form by the equation:

A space equals space A subscript 0 space e to the power of negative lambda t end exponent

  • Where:

    • A = activity at a certain time t (Bq)

    • A subscript 0 = initial activity (Bq)

  • The received count rate C is related to the activity of the sample, hence it can also be represented in exponential form by the equation:

C space equals space C subscript 0 space e to the power of negative lambda t end exponent

  • Where:

    • C = count rate at a certain time t (counts per minute or cpm)

    • C subscript 0 = initial count rate (counts per minute or cpm)

The exponential function e

  • The symbol e represents the exponential constant

    • It is approximately equal to e = 2.718

  • On a calculator it is shown by the button e to the power of x

  • The inverse function of e to the power of x is ln space y, known as the natural logarithmic function

    • This is because, if e to the power of x space equals space y, then x space equals space ln space y

Worked Example

Strontium-90 decays with the emission of a beta-particle to form yttrium-90.

The decay constant of strontium-90 is 0.025 year -1.

Determine the activity A of the sample after 5.0 years, expressing the answer as a fraction of the initial activity A subscript 0.

[2]

Answer:

Step 1: Write out the known quantities

  • Decay constant, lambda space equals space 0.025 space year to the power of negative 1 end exponent

  • Time interval, t space equals space 5.0 space years

  • Both quantities have the same unit, so there is no need for conversion

Step 2: Write the equation for activity in exponential form

A space equals space A subscript 0 space e to the power of negative lambda t end exponent

Step 3: Rearrange the equation for the ratio between A and A subscript 0

A over A subscript 0 space equals space e to the power of negative lambda t end exponent

Step 4: Calculate the ratio A over A subscript 0

A over A subscript 0 space equals space e to the power of negative open parentheses 0.025 cross times 8 close parentheses end exponent [1 mark]

A over A subscript 0 space equals space 0.88 [1 mark]

  • Therefore, the activity of strontium-90 decreases by a factor of 0.88, or 12%, after 5 years

Using molar mass & the Avogadro constant

Molar mass

  • The molar mass, or molecular mass, of a substance is the mass of a substance, in grams, in one mole

    • Its unit is g mol-1

  • The number of moles from this can be calculated using the equation:

number space of space moles space open parentheses mol close parentheses space equals space fraction numerator mass space open parentheses straight g close parentheses over denominator molar space mass space open parentheses straight g space mol to the power of negative 1 end exponent close parentheses end fraction

Avogadro’s constant

  • Avogadro’s constant N subscript A is defined as:

The number of atoms in one mole of a substance; equal to 6.02 × 1023 mol-1

  • For example, 1 mole of sodium (Na) contains 6.02 × 1023 atoms of sodium

  • The number of atoms, or nuclei, can be determined using the equation:

number space of space nuclei space equals space fraction numerator mass space cross times space N subscript A over denominator molar space mass end fraction

Worked Example

Americium-241 is an artificially produced radioactive element that emits α-particles.

In a smoke detector, a sample of americium-241 of mass 5.1 µg is found to have an activity of 5.9 × 105 Bq. The supplier’s website says the americium-241 in their smoke detectors initially has an activity level of 6.1 × 105 Bq.

Determine:

(a) the number of nuclei in the sample of americium-241 [2]

(b) the decay constant of americium-241 [2]

(c) the age of the smoke detector in years [3]

Answer:

Part (a)

Step 1: Write down the known quantities

  • Mass space equals space 5.1 space straight mu straight g space equals space 5.1 space cross times space 10 to the power of negative 6 end exponent space straight g

  • Molecular mass of americium = 241

  • Avogadro constant, N subscript A space equals space 6.02 space cross times space 10 to the power of 23 space mol to the power of negative 1 end exponent

Step 2: Write down the equation relating number of nuclei, mass and molecular mass

N space equals space fraction numerator mass space cross times space N subscript A over denominator molar space mass end fraction

Step 3: Calculate the number of nuclei

N space equals space fraction numerator open parentheses 5.1 space cross times space 10 to the power of negative 6 end exponent close parentheses space cross times space open parentheses 6.02 space cross times space 10 to the power of 23 close parentheses over denominator 241 end fraction [1 mark]

N space equals space 1.27394 space cross times space 10 to the power of 16 space equals space 1.27 space cross times space 10 to the power of 16 space open parentheses 3 space straight s. straight f. close parentheses [1 mark]

Part (b)

Step 1: Write down the known quantities

  • Activity, A space equals space 5.9 space cross times space 10 to the power of 5 space Bq

  • Number of nuclei, N space equals space 1.27394 space cross times space 10 to the power of 16

Step 2: Write the equation for activity

Activity: A space equals space lambda N

Step 3: Rearrange for decay constant λ and calculate the answer

lambda space equals space fraction numerator space A over denominator N end fraction space equals space fraction numerator 5.9 space cross times space 10 to the power of 5 over denominator 1.27394 space cross times space 10 to the power of 16 end fraction [1 mark]

lambda space equals space 4.63129 space cross times space 10 to the power of negative 11 end exponent space straight s to the power of negative 1 end exponent space equals space 4.63 space cross times space 10 to the power of negative 11 end exponent space straight s to the power of negative 1 end exponent space open parentheses 3 space straight s. straight f. close parentheses [1 mark]

Part (c)

Step 1: Write down the known quantities

  • Activity, A space equals space 5.9 space cross times space 10 to the power of 5 space Bq

  • Initial activity, A subscript 0 space equals space 6.1 space cross times space 10 to the power of 5 space Bq

  • Decay constant, lambda space equals space 4.63129 space cross times space 10 to the power of negative 11 end exponent space straight s to the power of negative 1 end exponent

Step 2: Write the equation for activity in exponential form

A space equals space A subscript 0 space e to the power of negative lambda t end exponent

Step 3: Rearrange for time t

A over A subscript 0 space equals space e to the power of negative lambda t end exponent

ln space open parentheses A over A subscript 0 close parentheses space equals space minus lambda t

t space equals space minus 1 over lambda ln space open parentheses A over A subscript 0 close parentheses space [1 mark]

Step 4: Calculate the age of the smoke detector and convert to years

t space equals space minus fraction numerator 1 over denominator 4.63129 space cross times space 10 to the power of negative 11 end exponent end fraction space cross times space ln space open parentheses fraction numerator 5.9 space cross times space 10 to the power of 5 over denominator 6.1 space cross times space 10 to the power of 5 end fraction close parentheses space equals space 7.1981 space cross times space 10 to the power of 8 space straight s [1 mark]

t space equals space fraction numerator 7.1981 space cross times space 10 to the power of 8 over denominator 24 space cross times space 60 space cross times space 60 space cross times space 365 end fraction space equals space 22.8 space years space open parentheses 3 space straight s. straight f. close parentheses [1 mark]

  • Therefore, the smoke detector is 22.8 years old

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Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Tim

Reviewer: Tim

Expertise: Content Creator

Timothy graduated with a first class degree in Mathematics and Physics from the University of Warwick. After working as a postgraduate researcher, Timothy has worked as a content creator for various online revision platforms, creating physics resources for a range of levels and exam boards.