Emission & Absorption Spectra in Stars (AQA A Level Physics): Revision Note

Exam code: 7408

Katie M

Written by: Katie M

Reviewed by: Tim

Updated on

Guided study available on this topic

Understand this topic with deeper explanations and understanding checks.

Emission & absorption spectra in stars

  • There are three types of light spectra:

    • continuous emission spectra

    • emission line spectra

    • absorption line spectra

  • Continuous spectrum: created when photons of all wavelengths are emitted

    • Appearance: a broad range of colours (depending on a star's temperature)

    • Produced by: hot, dense sources, such as the cores of stars

  • Emission spectrum: created when photons are emitted by excited electrons in a hot gas

    • Appearance: discrete wavelengths represented by coloured lines on a black background

    • Produced by: hot, low-pressure gases, such as a nebula surrounding a star

  • Absorption spectrum: created when photons are absorbed by electrons in a cool gas

    • Appearance: discrete wavelengths represented by dark lines on a continuous spectrum

    • Produced by: light passing through cool, low-pressure gases, such as the photosphere of a star

  • Note: the lines in an absorption spectrum correspond to the same lines in the emission spectrum of the same element

High-density hot matter through a diffraction grating produces a continuous rainbow. Low-density hot gas through a diffraction grating produces coloured lines on a black screen called an emission spectrum. High density hot matter passing through cool, low-density gas and a diffraction grating produces dark lines across a rainbow called an absorption spectrum.
An absorption spectrum is the combination of an emission spectrum on top of a continuous spectrum

Chemical composition of a star

  • Stellar spectral lines are caused by the interactions between photons and the atoms present in gaseous layers of stars

  • Photons produced by fusion reactions in a star’s core move towards the layers of gas in the outer atmosphere of the star

    • The photons produced in the core form a continuous spectrum

    • Photons are absorbed by the gas atoms, which excite and re-emit other photons of various frequencies in random directions

Hydrogen absorption spectrum showing dark lines at 410, 434, 486 and 656 nanometres across a continuous spectrum, with wavy photons promoting electrons between energy levels n = 1 to n = 4.
An absorption line will appear in a spectrum if an absorbing material is placed between a source and the observer
  • Each gas produces a unique pattern of spectral lines due to the specific transition between the element’s energy levels

    • The presence of absorption lines in a star’s spectrum act as fingerprints

    • They can be used to determine the presence of a certain element within the star 

  • The chemical composition of a star can be investigated even when extremely distant

    • If the element is present in the star, its characteristic pattern of spectral lines will appear as dark lines in the absorption line spectrum of the star

  • The Sun is predominantly made up of hydrogen and helium gas

    • This can be verified by comparing the emission line spectra of hydrogen and helium with the absorption line spectrum of the Sun

The hydrogen spectrum

  • Each element produces its own unique set of lines corresponding to specific energy level transitions

  • The spectrum of hydrogen was the first to be studied in great detail

Diagram of the full hydrogen spectrum showing spectral-line series by wavelength. Pfund, Brackett and Ritz–Paschen in infrared, Balmer in visible light, and Lyman in ultraviolet. Wavelength runs from 5000 to 100 nanometres.
The full hydrogen spectrum shows sets of lines representing specific energy level transitions
  • In spectra of hydrogen:

    • The Lyman series converges on the ground state n = 1

    • The Balmer series converges on the second energy level n = 2

    • The Ritz-Paschen converges on the third energy level n = 3, and so on

  • The Lyman series photons will have the most energy since they have the shortest wavelength

  • The Pfund series photons will have the least energy since they have the longest wavelength

  • Note: only the Balmer series needs to be remembered for this course; the others are mentioned here for context

Energy-level diagram for hydrogen, n = 1 to n = 8, showing downward electron transitions. Lyman to n = 1 (ultraviolet), Balmer to n = 2 (visible), Paschen to n = 3, Brackett to n = 4 and Pfund to n = 5 (infrared).
Each series of lines in the hydrogen spectrum ends on a different energy level
  • The discovery of these electron transitions has enabled astronomers to study the nature and chemical composition of objects in the Universe

Worked Example

Which of the following electron transitions in a hydrogen atom would result in the emission of visible light?

A. n = 1 to n = 2

B. n = 2 to n = 3

C. n = 2 to n = 1

D. n = 3 to n = 2

[1]

Answer:

  • A photon is emitted when an electron moves from a higher energy level to a lower energy level

    • This eliminates options A & B

  • Emission in the visible region occurs for an electron transitioning from any higher energy level to n = 2

  • Therefore, the transition n = 3 to n = 2 would result in the emission of visible light

  • This is option D [1 mark]

Worked Example

Explain why:

(a) Hot, dense sources produce continuous spectra [1]

(b) Hot, low pressure gases produce emission spectra [1]

(c) Hot, dense sources observed through cool, low pressure gases produce absorption spectra [1]

Answer:

Part (a)

  • Hot, dense sources, such as the cores of stars, produce continuous spectra because:

    • In a hot, dense material, the atoms or molecules are so close together that they interact with one another

    • This leads to a spread of energy states that are not clearly defined

    • Therefore, photons of all frequencies are emitted leading to an uninterrupted band of colour [1 mark]

Part (b)

  • Hot, low pressure gases produce emission line spectra, because:

    • Hot gases produce emission line spectra when photons are emitted due to the transition of electrons between discrete energy levels in atoms of the gas

    • The line spectrum has certain, fixed frequencies related to the differences in energy between the various energy levels of the atoms of the gas

    • In a low pressure gas, the atoms or molecules are not close together

    • This means the energy levels of the gas atoms or molecules are clearly quantised and well-defined

    • Therefore, only photons which correspond to the differences in energy between the energy levels of a bound electron are seen [1 mark]

Part (c)

  • Hot, dense sources observed through cold gases produce absorption spectra because: 

    • Atoms of different elements in the cold gas absorb energy emitted from the hot source but only at particular energy values

    • These particular energy values correspond to the differences in energy between the energy levels of a bound electron

    • This means that particular frequencies of light are absorbed, creating black lines in the continuous emission spectrum [1 mark]

Examiner Tips and Tricks

Given an absorption line spectrum for a specific star, you can be asked to identify a star of similar chemical composition. It is important to pay attention to the spacing between the lines to be able to correctly identify the most similar star to the given one.

Unlock more, it's free!

Join the 100,000+ Students that ❤️ Save My Exams

the (exam) results speak for themselves:

Build on this topic

Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Tim

Reviewer: Tim

Expertise: Content Creator

Timothy graduated with a first class degree in Mathematics and Physics from the University of Warwick. After working as a postgraduate researcher, Timothy has worked as a content creator for various online revision platforms, creating physics resources for a range of levels and exam boards.