Decay Equations (AQA A Level Physics): Revision Note

Exam code: 7408

Katie M

Written by: Katie M

Reviewed by: Tim

Updated on

Guided study available on this topic

Understand this topic with deeper explanations and understanding checks.

Changes in N and Z by radioactive decay

  • There are four reasons why a nucleus might become unstable, and these determine which decay mode will occur:

    • too many neutrons = beta-minus emission

    • too many protons = beta-plus emission or electron capture

    • too many nucleons = alpha emission

    • too much energy = gamma emission

If there are too many neutrons...

  • Beta-minus (β−) emission occurs

  • One of the neutrons in the nucleus changes into a proton and a β− particle (an electron) and antineutrino is released

  • The nucleon number is constant

    • The neutron number (N) decreases by 1

    • The proton number (Z) increases by 1

  • The general decay equation for β− emission is:

XZA → β−10 + YZ+1A + ve

Graph of beta-minus decay on an N–Z diagram. The arrow moves one square down and one square right, showing neutron number changes to N−1 and proton number to Z+1.
In beta-minus decay, N decreases by 1 and Z increases by 1

If there are too many protons...

  • Beta-plus (β+) emission or electron capture occurs

  • In beta-plus decay:

    • A proton changes into a neutron and a β+ particle (a positron) and neutrino are released

  • In electron capture:

    • An orbiting electron is taken in by the nucleus and combined with a proton causing the formation of a neutron and neutrino

  • In both types of decay, the nucleon number stays constant

    • The neutron number (N) increases by 1

    • The proton number (Z) decreases by 1

  • The general decay equation for β+ emission is:

XZA → β+10 + YZ−1A + ve

An N–Z graph of beta-plus decay, with neutron number N increasing by 1 and proton number Z decreasing by 1. The arrow moves one square up and one square left, labelled β⁺.
In beta-plus decay, N increases by 1 and Z decreases by 1
  • The decay equation for electron capture is:

XZA + e−10  → YZ−1A + ve

If there are too many nucleons...

  • Alpha (α) emission occurs

  • An α particle is a helium nucleus

  • The nucleon number decreases by 4 and the proton number decreases by 2

    • The neutron number (N) decreases by 2

    • The proton number (Z) decreases by 2

  • The general decay equation for α emission is:

XZA → α24 + YZ−2A−4

An N–Z graph of alpha decay where the arrow moves down and left from the parent nucleus to the daughter nucleus. Neutron number N becomes N−2 and proton number Z becomes Z−2.
In alpha decay, N decreases by 2 and Z decreases by 2

If there is too much energy...

  • Gamma (γ) emission occurs

  • A gamma particle is a high-energy electromagnetic radiation

  • This usually occurs after a different type of decay, such as alpha or beta decay

  • This is because the nucleus becomes excited and has excess energy

Representing nuclear processes graphically

  • In summary, alpha decay, beta decay and electron capture can be represented on an N–Z graph as follows:

N–Z diagram summarising the different types of radioactive decay. Arrows show alpha: N−2, Z−2; beta-minus: N−1, Z+1; beta-plus: N+1, Z−1.
Representing nuclear processes graphically

Worked Example

Plutonium-239 is a radioactive isotope that contains 94 protons and emits α particles to form a radioactive isotope of uranium. This isotope of uranium emits α particles to form an isotope of thorium which is also radioactive.

(a) Write two equations to represent the decay of plutonium-239 and the subsequent decay of uranium. [2]

(b) Predict the decay mode of the thorium isotope. [1]

(c) Draw the decay chain from plutonium-239 to the daughter product of thorium decay on an N–Z graph. [3]

Answer:

Part (a)

Step 1: Write down the general equation of alpha decay

XZA → YZ−2A−4 + α24

Step 2: Write down the decay equation of plutonium into uranium

Pu94239 → U92235 + α24 [1 mark]

Step 3: Write down the decay equation of uranium into thorium

U92235 → Th90231 + α24 [1 mark]

Part (b)

  • Plutonium, 239Pu

    • Number of neutrons: 239 – 94 = 145

    • Neutron-nucleon ratio: 145 / 239 = 0.607

  • Uranium, 235U

    • Number of neutrons: 235 – 92 = 143

    • Neutron-nucleon ratio: 143 / 235 = 0.609

  • Thorium, 231Th

    • Number of neutrons: 231 – 90 = 141

    • Neutron-nucleon ratio: 141 / 231 = 0.610

  • Thorium-231 is neutron-rich compared to uranium-235 and plutonium-239

  • Therefore, it must be a β– emitter [1 mark]

Part (c)

Completed N–Z graph showing Pu-239 (94,145) → U-235 (92,143) → Th-231 (90,141) by alpha decay, then beta-minus decay to a daughter nucleus at (91,140). N is vertical and Z horizontal.

[1 mark]

  • The key features to draw on an N–Z graph are:

    • values for neutron number (N) on the vertical axis

    • values for proton number (Z) on the horizontal axis

    • labels for the isotopes e.g. 239Pu, 235U, 231Th

    • arrows showing the direction of the decay [1 mark]

    • labels for the type of emission e.g. α, β− [1 mark]

Examiner Tips and Tricks

Watch out for the vertical axis for the N-Z graph. Instead of N for number of neutrons, this is sometimes labelled as N for nucleon number (total protons and neutrons) which means the decays will be represented slightly differently.

Unlock more, it's free!

Join the 100,000+ Students that ❤️ Save My Exams

the (exam) results speak for themselves:

Build on this topic

Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Tim

Reviewer: Tim

Expertise: Content Creator

Timothy graduated with a first class degree in Mathematics and Physics from the University of Warwick. After working as a postgraduate researcher, Timothy has worked as a content creator for various online revision platforms, creating physics resources for a range of levels and exam boards.