Decay Equations (AQA A Level Physics): Revision Note

Exam code: 7408

Katie M

Written by: Katie M

Reviewed by: Caroline Carroll

Updated on

Changes in N and Z by Radioactive Decay

  • There are four reasons why a nucleus might become unstable, and these determine which decay mode will occur

  1. Too many neutrons = beta-minus emission

  2. Too many protons = beta-plus emission or electron capture

  3. Too many nucleons = alpha emission

  4. Too much energy = gamma emission

If there are too many neutrons...

  • Beta-minus-) emission occurs

  • One of the neutrons in the nucleus changes into a proton and a β- particle (an electron) and antineutrino is released

  • The nucleon number is constant

    • The neutron number (N) decreases by 1

    • The proton number (Z) increases by 1

  • The general decay equation for β- emission is:

XZA  β10 + YZ+1A + ve

Beta Minus Decay Graph, downloadable AS & A Level Physics revision notes

Representing beta-minus decay graphically

If there are too many protons...

  • Beta-plus+) emission or electron capture occurs

  • In beta-plus decay:

    • A proton changes into a neutron and a β+ particle (a positron) and neutrino are released

  • In electron capture:

    • An orbiting electron is taken in by the nucleus and combined with a proton causing the formation of a neutron and neutrino

  • In both types of decay, the nucleon number stays constant

    • The neutron number (N) increases by 1

    • The proton number (Z) decreases by 1

  • The general decay equation for β+ emission is:

XZA  β+10 + YZ1A + ve

Beta Plus Decay Graph, downloadable AS & A Level Physics revision notes

Representing beta-plus decay graphically

  • The decay equation for electron capture is:

XZA + e10   YZ1A + ve

If there are too many nucleons...

  • Alpha (α) emission occurs

  • An α particle is a helium nucleus

  • The nucleon number decreases by 4 and the proton number decreases by 2

    • The neutron number (N) decreases by 2

    • The proton number (Z) decreases by 2

  • The general decay equation for α emission is:

XZA  α24 + YZ2A4

Alpha Decay Graph, downloadable AS & A Level Physics revision notes

Representing alpha decay graphically

If there is too much energy...

  • Gamma (γ) emission occurs

  • A gamma particle is a high-energy electromagnetic radiation

  • This usually occurs after a different type of decay, such as alpha or beta decay

  • This is because the nucleus becomes excited and has excess energy

Representing Nuclear Processes Graphically

  • In summary, alpha decay, beta decay and electron capture can be represented on an N–Z graph as follows:

NZ Decay Graph, downloadable AS & A Level Physics revision notes

Representing nuclear processes graphically

Worked Example

Plutonium-239 is a radioactive isotope that contains 94 protons and emits α particles to form a radioactive isotope of uranium. This isotope of uranium emits α particles to form an isotope of thorium which is also radioactive.

(a) Write two equations to represent the decay of plutonium-239 and the subsequent decay of uranium.

(b) Predict the decay mode of the thorium isotope.

(c) Draw the decay chain from plutonium-239 to the daughter product of thorium decay on an N–Z graph.

Answer:

Part (a)

Step 1: Write down the general equation of alpha decay

XZA  YZ2A4 + α24

Step 2: Write down the decay equation of plutonium into uranium

Pu94239  U92235 + α24

Step 3: Write down the decay equation of uranium into thorium

U92235  Th90231 + α24

Part (b)

  • Plutonium, 239Pu

    • Number of neutrons: 239 – 94 = 145

    • Neutron-nucleon ratio: 145 / 239 = 0.607

  • Uranium, 235U

    • Number of neutrons: 235 – 92 = 143

    • Neutron-nucleon ratio: 143 / 235 = 0.609

  • Thorium, 231Th

    • Number of neutrons: 231 – 90 = 141

    • Neutron-nucleon ratio: 141 / 231 = 0.610

  • Thorium-231 is neutron-rich compared to uranium-235 and plutonium-239

  • Therefore, it must be a β emitter

Part (c)

WE - NZ Decay Graph, downloadable AS & A Level Physics revision notes
  • The key features to draw on an N–Z graph are:

    • Values for neutron number (N) on the vertical axis

    • Values for proton number (Z) on the horizontal axis

    • Labels for the isotopes eg. 239Pu, 235U, 231Th

    • Arrows showing the direction of the decay

    • Labels for the type of emission eg. α, β

Examiner Tips and Tricks

Watch out for the vertical axis for the N-Z graph. Instead of N for number of neutrons this is sometimes labelled as N for nucleon number (total protons and neutrons) which means the decays will be represented slightly differently.

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Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Caroline Carroll

Reviewer: Caroline Carroll

Expertise: Head of Content Delivery

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about delivering high-quality resources to help students achieve their full potential.