The de Broglie Wavelength (AQA A Level Physics): Revision Note

Exam code: 7408

Katie M

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The de Broglie wavelength

  • The de Broglie equation relates wavelength (a property of waves) to momentum (a property of matter)

  • In the electron diffraction experiment:

    • Increasing the speed of electrons, and hence their momentum, causes the angle of diffraction to decrease (as seen by the decrease in the diameter of the diffraction rings)

  • This is in agreement with wave theory, where the angle of diffraction decreases as the wavelength decreases

    • Therefore, the greater the momentum of the particle, the smaller the de Broglie wavelength

  • Using ideas based on quantum theory and Einstein’s theory of relativity, de Broglie suggested that the momentum (p) of a particle and its associated wavelength (λ) are related by the equation:

λ = hp

  • Using momentum  p = mv, the de Broglie wavelength can be written in terms of the speed of a moving particle:

λ = hmv

  • Using kinetic energy E = 12mv2, momentum and kinetic energy can be related by:

Energy:  E = 12mv2 = mv22 = p22m 

Momentum:   p = 2mE

  • Combining this with the de Broglie equation gives a form which relates the de Broglie wavelength of a particle to its kinetic energy:

λ = h2mE

  • Where:

    • λ = the de Broglie wavelength (m)

    • h = Planck’s constant (J s)

    • p = momentum of the particle (kg m s-1)

    • E = kinetic energy of the particle (J)

    • m = mass of the particle (kg)

    • v = speed of the particle (m s-1)

Worked Example

A proton and an electron are each accelerated from rest through the same potential difference.

Determine the ratio: de Broglie wavelength of the protonde Broglie wavelength of the electron

  • Mass of a proton = 1.67 × 10–27 kg

  • Mass of an electron = 9.11 × 10–31 kg

[3]

Answer:

Step 1: Determine how the proton and electron can be related via their mass

  • The only information given is the mass of the proton and the electron

  • When the proton and electron are accelerated through a potential difference, their kinetic energy will increase

  • Kinetic energy can therefore be used to relate them via their mass

Step 2: Write out the equation for the de Broglie wavelength in terms of the kinetic energy of the particle

  • The de Broglie wavelength

λ = hmv = hp

  • Kinetic energy

E = 12mv2 = mv22 = p22m

  • Kinetic energy in terms of momentum

p = 2mE

  • Substitute the expression for momentum into the de Broglie wavelength equation

λ = h2mE

Step 3: Find the proportional relationship between the de Broglie wavelength and the mass of the particle

λ = h2mE = k1m

  • Where k is a constant

    • Since h is constant, and E is equal, then:

λ ∝ 1m [1 mark]

Step 4: Calculate the ratio

λpλe = 1mp ÷ 1me = 1mp × me1 = memp [1 mark]

λpλe = memp = 9.11×10−311.67×10−27

λpλe = 0.0234 (3 s.f.) [1 mark]

  • This means that the de Broglie wavelength of the proton is 0.0234 times smaller than that of the electron

  • Or that the de Broglie wavelength of the electron is about 40 times larger than that of the proton

Examiner Tips and Tricks

Particles with a greater mass, such as a proton, have a greater momentum. The greater the momentum, the smaller the de Broglie wavelength. Always perform a logic check on your answer to check that it makes sense.

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Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Tim

Reviewer: Tim

Expertise: Content Creator

Timothy graduated with a first class degree in Mathematics and Physics from the University of Warwick. After working as a postgraduate researcher, Timothy has worked as a content creator for various online revision platforms, creating physics resources for a range of levels and exam boards.