Atomic Structure (AQA A Level Physics): Revision Note

Exam code: 7408

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Atomic structure

  • All matter is made from atoms

  • Atoms are made up of three types of particles:

    • Protons

    • Neutrons

    • Electrons

Atomic structure diagram showing a nucleus with three protons (red) and four neutrons (green), surrounded by two electron shells containing three electrons (blue).
Protons and neutrons are found in the nucleus of an atom while electrons orbit the nucleus
  • The properties of each particle in SI units are shown in the table below:

Particle

Charge / C

Mass / kg

Proton

+1.60 × 10−19

1.67(3) × 10−27

Neutron

0

1.67(5) × 10−27

Electron

−1.60 × 10−19

9.11 × 10−31

  • The relative properties of each particle are shown in the table below:

Particle

Relative charge

Relative mass

Proton

+1

1

Neutron

0

1

Electron

-1

1/2000 (negligible)

  • A stable atom is neutral (it has no charge)

  • Since protons and electrons have the same charge, but opposite signs, a stable atom has an equal number of both for the overall charge to remain neutral

Examiner Tips and Tricks

Remember not to mix up the ‘atom’ and the ‘nucleus’. The ‘atom’ consists of the nucleus and electrons. The ‘nucleus’ just consists of the protons and neutrons in the middle of the atom, not the electrons.

Specific charge

  • In physics, ‘specific’ refers to the characteristic of a property of a substance

    • It is usually stated as a ratio i.e. per unit mass, length, area, volume etc.

    • For example, specific heat capacity refers to the thermal energy per unit mass of a substance

  • In atomic physics, specific charge is defined as:

The ratio of the total charge of a particle to its mass

  • It can be calculated using the equation:

specific charge = chargemass = Qm

  • Specific charge is measured in units of coulombs per kilogram (C kg–1)

  • Values for the specific charge of the electron and proton are given on the datasheet as the ‘charge / mass ratio’

    • The specific charge of the electron = eme = 1.76 × 1011 C kg−1

    • The specific charge of the proton = emp = 9.58 × 107 C kg−1

Calculating specific charge

  • The specific charge of an ion or a nucleus can also be found

    • Charge of a proton or electron, e = 1.60 × 10–19 C

    • Mass of a proton, mp (or neutron, mn) = 1.67 × 10–27 kg

  • To calculate the specific charge of an ion:

    • Charge = Total number of electrons added / removed × (1.60 × 10–19 C)

    • Mass = Total number of nucleons × (1.67 × 10–27 kg)

  • To calculate the specific charge of a nucleus:

    • Charge = Total charge of the protons × (1.60 × 10–19 C)

    • Mass = Total number of nucleons × (1.67 × 10–27 kg)

  • The number of nucleons is given by the mass number of the ion or nucleus

This ion has seven nucleons and two added electrons (each with a charge of −1.60 × 10^-19 C). Each nucleon has a mass 1.67 × 10^-27 kg. The nucleus has seven nucleons and the charge is given by the three protons (each with a charge of +1.60 × 10^-19 C).
How the total charge and mass are calculated depends on whether you are calculating the specific charge for an ion or a nucleus

Worked Example

An atom of Mg1224 gains 2 electrons.

What is the specific charge of the ion?

[3]

Answer:

Step 1: List the relevant quantities from the data booklet:

  • Charge of an electron = −1.60 × 10−19 C

  • Mass of a proton = 1.67 × 10−27 kg

Step 2: Write the specific charge equation:

specific charge = Qm

Step 3: Calculate the total mass of the ion:

  • The notation for the magnesium ion can be written as:

Mg2−1224

  • This tells us the ion contains 24 nucleons in total

  • So, the total mass can be calculated using:

total mass = nucleon (mass) number × mass of one nucleon

total mass = 24 × (1.67 × 10−27)

total mass = 4.0 × 1026 kg [1 mark]

Step 4: Calculate the total charge on the ion:

  • Before gaining 2 electrons, the magnesium atom was electrically neutral

  • So, the total charge on the ion is equal to the charge of 2 electrons, which is:

total charge = 2 × (−1.60 × 10−19)

total charge = −3.2 × 10−19 C [1 mark]

Step 5: Substitute the values into the equation:

specific charge = −3.2 × 10−194.0 × 10−26

specific charge = −8.0 × 106 C kg−1 (2 s.f.) [1 mark]

Examiner Tips and Tricks

Sometimes you might be asked if the specific charge is positive or negative for an ion. Since the electron has a negative charge, the rules are as follows:

  • If there is a gain in electrons, the specific charge will be negative

  • If there is a loss of electrons, the specific charge will be positive

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Katie M

Author: Katie M

Expertise: Curriculum Expert

Katie has always been passionate about the sciences, and completed a degree in Astrophysics at Sheffield University. She decided that she wanted to inspire other young people, so moved to Bristol to complete a PGCE in Secondary Science. She particularly loves creating fun and absorbing materials to help students achieve their exam potential.

Tim

Reviewer: Tim

Expertise: Content Creator

Timothy graduated with a first class degree in Mathematics and Physics from the University of Warwick. After working as a postgraduate researcher, Timothy has worked as a content creator for various online revision platforms, creating physics resources for a range of levels and exam boards.