Organic Analytical Techniques (Edexcel International A Level (IAL) Chemistry): Exam Questions

Exam code: YCH11

19 mins8 questions
11 mark

In HPLC, the mobile and stationary phases are

 

 

Mobile phase

Stationary phase

A

gas

liquid

B

gas

solid

C

liquid

gas

D

liquid

solid

    1
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    1 mark

    The mass spectrum of the compound shown is obtained using a high resolution mass spectrometer.

    q7-paper-5-jan-2022-edexcel-ial-chemistry

    What is the mass to charge ratio, m/ z, of the molecular ion of this compound?

    [Ar values: H = 1.0078    C = 12.0000    O = 15.9949]

    • 92.0261

    • 92.0312

    • 93.0339

    • 93.0390

    2a
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    1 mark

    This question is about chromatography.

    A spot caused by an amino acid has moved 42 mm from the baseline of a paper chromatogram. The Rf value for the amino acid under these conditions is 0.62.

    What is the distance moved by the solvent?

    • 680 mm

    • 68 mm

    • 42 mm

    • 26 mm

    2b1 mark

    In gas chromatography, GC, which of these would be the most suitable carrier gas?

    • argon

    • hydrogen

    • methane

    • oxygen

    31 mark

    How many peaks are there in the carbon-13 (13C) NMR spectrum of methylcyclohexane?

    q15-paper-5-june-2021-edexcel-ial-chemistry
    • one

    • three

    • five

    • seven

    41 mark

    In gas chromatography, a gas containing a mixture is passed over a liquid stationary phase. The main reason a mixture is separated into its components is because they have different

    • boiling temperatures

    • forces of attraction to the liquid

    • relative molecular masses

    • volatilities

    51 mark

    In the high resolution proton NMR spectrum of propan-2-ol, CH3CHOHCH3 there are

    • one singlet, one doublet and a heptet

    • one singlet, two doublets and a heptet

    • two singlets and two triplets

    • three singlets and a quartet

    61 mark

    A mixture of organic compounds was analysed using thin-layer chromatography.

    The Rf value was 0.92 for one of the components in the mixture.

    What can be deduced about the attractions between that component and the stationary and mobile phases?

     

     

    Attraction between component and stationary phase

    Attraction between component and mobile phase

    A

    strong

    strong

    B

    strong

    weak

    C

    weak

    weak

    D

    weak

    strong