Group 7 (Edexcel International A Level (IAL) Chemistry): Exam Questions

Exam code: YCH11

38 mins19 questions
1
1 mark

Which statement about the Group 7 elements chlorine, bromine and iodine is not correct?

  • boiling temperature increases down the group

  • reactivity increases down the group

  • first ionisation energy decreases down the group

  • electronegativity decreases down the group

2
1 mark

Which silver halides are soluble in concentrated aqueous ammonia?

  • AgBr and AgI

  • AgCl and AgI

  • AgCl and AgBr

  • AgCl only

3
1 mark

Which of these increases as Group 7 is descended?

  • oxidising ability of the molecular halogens

  • reducing ability of the halide ions

  • electrostatic attraction between the nucleus and outer shell of electrons

  • electronegativity of the halogen atoms

4
1 mark

When iodine is dissolved in a non-polar organic solvent, the solution formed is

  • purple

  • orange

  • colourless

  • brown

5
1 mark

Chlorine reacts with cold dilute aqueous sodium hydroxide.

Cl2 (aq) + 2NaOH (aq) → NaCl (aq) + NaClO (aq) + H2O (l)

Which statement about this reaction is correct?

  • Chlorine is only oxidised

  • The oxidation number of chlorine in Cl2 is −1

  • The oxidation number of chlorine in NaClO is 0

  • Chlorine is both oxidised and reduced in this reaction

1a
1 mark

This question is about the reaction of potassium iodide with concentrated sulfuric acid.

Which of these would not be seen?

  • misty fumes

  • black solid

  • yellow solid

  • dense white smoke

1b
1 mark

One of the reaction products is the gas H2S. What is the change in oxidation number of sulfur as H2S forms?

  • −8

  • −6

  • −2

  • +6

2
1 mark

Four tests used to identify ions are shown:

1   flame test
2   addition of acidified barium nitrate solution
3   addition of acidified silver nitrate solution
4   addition of sodium hydroxide solution, then testing any gas with indicator paper

Which tests could be used to positively identify the ions in ammonium chloride?

  • 1 and 2

  • 1 and 3

  •  2 and 4

  • 3 and 4

3
1 mark

Solid potassium bromide reacts with concentrated sulfuric acid.

Which of these substances does not form?

  • bromine

  • hydrogen bromide

  • hydrogen sulfide

  • sulfur dioxide

4
1 mark

A student adds chlorine water to an aqueous solution of an unknown potassium halide. A small volume of cyclohexane (density = 0.79 g cm–3) is then added and the mixture is shaken thoroughly.

The upper layer turns purple/violet.

Which halide was present in the original solution?

  • KBr

  • KCl

  • KF

  • KI

5
1 mark

A solution containing both bromine and chlorine produces bromate ions, BrO3−, in two reactions.

Reaction 1: Br2 + H2O → HBr + HBrO

Reaction 2: 3HBrO + Cl2 → 2Cl− + BrO3− + Br2 + 3H+

Which row shows which statements are correct (✓) and which are incorrect (✗)?

Chlorine is reduced in reaction 2

Bromine is reduced in both reaction 1 and reaction 2

Bromine is oxidised in reaction 2 only

A

✓

✗

✗

B

✓

✓

✗

C

✗

✓

✓

D

✓

✓

✓

    6
    1 mark

    Two experiments are carried out with potassium chloride.

    Experiment 1: Aqueous silver nitrate is added to aqueous potassium chloride, followed by an excess of dilute aqueous ammonia. The final observation is X.

    Experiment 2: Concentrated sulfuric acid is added to solid potassium chloride. The gas produced is bubbled into aqueous potassium iodide. The final observation is Y.

    Which row identifies observations X and Y?

    X

    Y

    A

    colourless solution

    brown solution

    B

    colourless solution

    colourless solution

    C

    white precipitate

    brown solution

    D

    white precipitate

    colourless solution

      7
      1 mark

      The acid HIO disproportionates in aqueous solution. In the equation, q, r, s and t are whole numbers in their lowest ratio.

      qHIO (aq) → rI2 (aq) + sHIO3 (aq) + tH2O (l)

      Which row gives the values of r and s?

      r

      s

      A

      1

      2

      B

      2

      1

      C

      4

      1

      D

      4

      2

        8
        1 mark

        Chlorine reacts with hot aqueous sodium hydroxide to form sodium chloride and sodium chlorate(V).

        Which is the half-equation for the oxidation of chlorine in this reaction?

        • ½Cl2 + e− → Cl−

        • ½Cl2 + 2OH− → ClO− + H2O + e−

        • ½Cl2 + 6OH− → ClO3− + 3H2O + 5e−

        • Cl2 + 6OH− → ClO3− + 3H2O + 5e−

        9
        1 mark

        80 cm3 of hydrogen chloride gas is mixed with 50 cm3 of ammonia gas. The reaction goes to completion and all volumes are measured at r.t.p.

        The gas left at the end is then dissolved in water.

        Which row describes the volume of gas left and the solution formed?

        Volume of gas left / cm3

        Solution formed

        A

        30

        acidic

        B

        30

        alkaline

        C

        80

        acidic

        D

        80

        alkaline

          1
          1 mark

          0.515 g of a sodium halide, NaX, is dissolved in water. Excess aqueous silver nitrate is added, and 0.940 g of silver halide precipitate forms.

          A sample of solid NaX is then warmed with concentrated sulfuric acid.

          Which row identifies the halide ion and the observations with concentrated sulfuric acid?

          [Ar values: Na = 23.0 Cl = 35.5 Br = 79.9 Ag = 107.9]

          Halide ion

          Observations with concentrated sulfuric acid

          A

          chloride

          misty fumes only

          B

          chloride

          misty fumes and red-brown fumes

          C

          bromide

          misty fumes only

          D

          bromide

          misty fumes and red-brown fumes

            2
            1 mark

            Astatine is below iodine in Group 7.

            Solid sodium astatide, NaAt, is predicted to react with concentrated sulfuric acid in a similar way to solid sodium iodide.

            A redox product is a substance formed when an element is oxidised or reduced.

            Which row describes hydrogen astatide, HAt, and hydrogen sulfide, H2S, in this reaction?

            HAt

            H2S

            A

            not a redox product

            a redox product

            B

            not a redox product

            not formed

            C

            a redox product

            a redox product

            D

            a redox product

            not formed

              3
              1 mark

              2.84 g of chlorine reacts completely with excess hot aqueous sodium hydroxide.

              What is the mass of the sodium salt formed in which chlorine has a positive oxidation number?

              [Ar values: O = 16.0 Na = 23.0 Cl = 35.5]

              • 0.993 g

              • 1.42 g

              • 2.98 g

              • 4.26 g