Ionic & Metallic Bonding & Structure (Edexcel International A Level (IAL) Chemistry): Exam Questions

Exam code: YCH11

47 mins18 questions
1a
6 marks

This question is about the elements in Period 3 of the Periodic Table, and some of their compounds.

The atomic radii of six of the elements are given.

Symbol

Na

Mg

Al

Si

P

S

Cl

Ar

Atomic
number

11

12

13

14

15

16

17

18

Atomic radius
/ nm

0.191

0.160

0.130

 

 

0.102

0.099

 0.095

i) Plot a graph of atomic radius against atomic number.

(2)

q22a-paper-1-june-2021-edexcel-ial-chemistry

ii) Use the graph to estimate the atomic radius of silicon, Si.

(1)

iii) Suggest an explanation for the decrease in atomic radius as atomic number increases across a period.

(3)

1b
6 marks

The melting temperatures of sodium, sodium chloride and chlorine are given in the table.

Complete the table to show the type of structure, the type of bond or force broken on melting and the particles involved.

Substance

Sodium

Sodium chloride

Chlorine

Melting temperature / °C

98

801

−101

Type of structure

giant

 

simple molecular

Type of bond or force broken on melting

 

 

 

Particles involved

 

 

chlorine molecules

1c
4 marks

Solid phosphorus(V) chloride contains PCl4+ ions.

i) Draw a dot-and-cross diagram of a PCl4+ ion.

Show only outer shell electrons.

(1)

ii) Predict the shape of a PCl4+ ion.

Justify your answer.

(3)

Shape

............................................................................................

Justification

2a
2 marks

This question is about bonding and structure in a range of chlorides.

Draw a dot-and-cross diagram for magnesium chloride, MgCl2. Show outer shell electrons only.

2b
4 marks

Phosphorus pentachloride, PCl5, has the shape shown.

Chemical structure of phosphorus pentachloride (PCl5) showing central phosphorus atom bonded to five chlorine atoms in a trigonal bipyramidal shape.

Explain the shape of a PCl5 molecule and state its bond angles.

[4]

2c
5 marks

i) Explain why magnesium chloride, MgCl2, has more covalent character than barium chloride, BaCl2.

[2]

ii) Aluminium chloride can exist as the dimer Al2Cl6 in the gas phase. The dimer contains two dative (coordinate) covalent bonds.

State what is meant by a dative covalent bond, and draw the structure of Al2Cl6, clearly showing all bonds (including the dative covalent bonds).

[3]

2d
3 marks

Magnesium chloride conducts electricity in some physical states but not others.

Explain why MgCl2 does not conduct electricity when solid, but does conduct electricity when molten or in aqueous solution.

[3]