Calorimetry (SQA National 5 Chemistry): Revision Note

Exam code: X813 75

Richard Boole

Written by: Richard Boole

Reviewed by: Philippa Platt

Updated on

Calorimetry experiments

  • Different fuels release different quantities of energy when they burn

  • The amount of heat energy released by a fuel can be measured using a technique called calorimetry

  • A simple calorimetry experiment involves using the heat from a burning fuel to raise the temperature of a known mass of water

Experimental setup showing a copper can with water and thermometer, heated by a spirit burner. Includes an insulating lid and draught shields.
A simple experiment to measure the heat energy released by a fuel.
  • Two measurements are required for this experiment:

    • The mass of water being heated (m)

    • The temperature change of the water (ΔT)

  • These measurements, along with the specific heat capacity of water (c), are used in the Eh = cmΔT formula to calculate the heat energy released

Calorimetry calculations

  • To calculate the quantity of heat energy released, we use the formula given on page 3 of the SQA Data Booklet

The heat energy formula

Eh = cmΔT

  • Values in the equation:

    • Eh = the heat energy absorbed by the water (in kilojoules, kJ)

    • c = the specific heat capacity of the substance being heated

      • For water, this value is 4.18 (found in the Data Booklet)

    • m = The mass of the substance being heated (in kilograms, kg)

    • ΔT = The change in temperature (in degrees Celsius, °C)

      • ΔT = T(final) - T(initial)

How to use the heat energy formula

  • List all the variables (Eh, c, m, ΔT), identifying the one you need to find

    • Convert all masses to kilograms (kg) by dividing by 1000

    • Calculate the temperature change, if required

  • Substitute the known values into the formula

  • Rearrange the formula for the unknown value

  • Solve the formula for the unknown value

Examiner Tips and Tricks

This calculation is a very common source of errors in exams. You must use the correct units:

  • The mass of water (m) must be in kilograms (kg)

    • To convert grams to kg, divide by 1000

  • The final answer for Eh will be in kilojoules (kJ)

Worked Example

Calculating Eh:

When a fuel was burned, it was used to heat 200g of water. The temperature of the water rose from 20°C to 50°C. Calculate the heat energy absorbed by the water.

[2]

Answer:

  • List the variables:

    • Eh = ?

    • c = 4.18

    • m = 200 g = 0.2 kg

    • ΔT = 50 - 20 = 30 °C

  • Substitute the known values into the formula:

Eh = cmΔT

Eh = 4.18 x 0.2 x 30 [1 mark]

  • There is no rearrangement required for this calculation

  • Solve the formula for the unknown value:

Eh = 25.08 kJ [1 mark]

Worked Example

Calculating temperature change (ΔT):

50.16 kJ of heat energy was transferred to 1.2 kg of water. Calculate the temperature change of the water.

[2]

Answer:

  • List the variables:

    • Eh = 50.16

    • c = 4.18

    • m = 1.2 kg

    • ΔT = ?

  • Substitute the known values into the formula:

Eh = cmΔT

50.16 = 4.18 x 1.2 x ΔT [1 mark]

  • Rearrange the formula:

ΔT = fraction numerator 50.16 over denominator 4.18 cross times 1.2 end fraction

  • Solve the formula for the unknown value:

ΔT = 10 oC [1 mark]

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Richard Boole

Author: Richard Boole

Expertise: Chemistry Content Creator

Richard has taught Chemistry for over 15 years as well as working as a science tutor, examiner, content creator and author. He wasn’t the greatest at exams and only discovered how to revise in his final year at university. That knowledge made him want to help students learn how to revise, challenge them to think about what they actually know and hopefully succeed; so here he is, happily, at SME.

Philippa Platt

Reviewer: Philippa Platt

Expertise: Chemistry Content Creator

Philippa has worked as a GCSE and A level chemistry teacher and tutor for over thirteen years. She studied chemistry and sport science at Loughborough University graduating in 2007 having also completed her PGCE in science. Throughout her time as a teacher she was incharge of a boarding house for five years and coached many teams in a variety of sports. When not producing resources with the chemistry team, Philippa enjoys being active outside with her young family and is a very keen gardener