Activation Energy (DP IB Chemistry): Revision Note

Caroline Carroll

Written by: Caroline Carroll

Reviewed by: Philippa Platt

Updated on

Activation energy

What is activation energy?

  • For a reaction to take place, the reactant particles need to overcome a minimum amount of energy

    • This energy is called the activation energy (Ea)

  • In exothermic reactions, the reactants are higher in energy than the products

  • In endothermic reactions, the reactants are lower in energy than the products

 Energy profile of an exothermic reaction, showing Ea

The energy profile of an exothermic reaction shows the energy level of the reactants higher than the products
The diagram shows that the reactants are higher in energy than the products in the exothermic reaction

 Energy profile of an endothermic reaction, showing Ea

The energy profile of an endothermic reaction shows the energy level of the reactants lower than the products
The diagram shows that the reactants are lower in energy than the products in the endothermic reaction
  • Even if particles collide with the correct orientation, the reaction will not occur unless they have at least the minimum energy required, the activation energy (Eₐ)

  • For a collision to be successful, particles must both:

    • Collide in the correct orientation and

    • Have energy equal to or greater than the activation energy (Eₐ) of the reaction

Examiner Tips and Tricks

How to find the activation energy of a reverse reaction

  • You may be required to show or calculate the activation energy for a reverse reaction using a labelled energy profile like those above

  • The activation energy for the reverse reaction is found by:

For an exothermic reaction =  ∆H + Ea (forward)

For an endothermic reaction = Ea (forward) - ∆H

  • Calculations of the value of the activation energy from experimental data are not required at Standard Level but are required in Higher Level Chemistry

  • For more information on how to calculate activation energy, see our revision notes on Determining Activation Energy & the Arrhenius Factor

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Caroline Carroll

Author: Caroline Carroll

Expertise: Physics & Chemistry Subject Lead

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about creating high-quality resources to help students achieve their full potential.

Philippa Platt

Reviewer: Philippa Platt

Expertise: Chemistry Content Creator

Philippa has worked as a GCSE and A level chemistry teacher and tutor for over thirteen years. She studied chemistry and sport science at Loughborough University graduating in 2007 having also completed her PGCE in science. Throughout her time as a teacher she was incharge of a boarding house for five years and coached many teams in a variety of sports. When not producing resources with the chemistry team, Philippa enjoys being active outside with her young family and is a very keen gardener