Water & the Hydrogen Bond (Cambridge (CIE) A Level Biology): Revision Note

Exam code: 9700

Cara Head

Written by: Cara Head

Reviewed by: Alistair Marjot

Updated on

Water molecules: hydrogen bonds

  • Water is of great biological importance. It is the medium in which all metabolic reactions take place in cells

    • Between 70% to 95% of the mass of a cell is water

  • As 71% of the Earth’s surface is covered in water it is a major habitat for organisms

  • Water is composed of atoms of hydrogen and oxygen

    • One atom of oxygen combines with two atoms of hydrogen by sharing electrons so they are covalently bonded

  • Although water as a whole is electrically neutral the sharing of the electrons is uneven between the oxygen and hydrogen atoms

    • The oxygen atom attracts the electrons more strongly than the hydrogen atoms, resulting in:

      • A weak negatively charged region on the oxygen atom (δ-)

      • A weak positively charged region on the hydrogen atoms(δ+)

    • This results in the asymmetrical shape of water molecules

    • This separation of charge due to the electrons in the covalent bonds being unevenly shared is called a dipole

      • When a molecule has one end that is negatively charged and one end that is positively charged it is also a polar molecule

  • Water is a polar molecule

Diagram showing a water molecule with oxygen atom bonded to two hydrogen atoms, highlighting polar covalent bonds and a bond angle of about 105 degrees.
The covalent bonds of water make it a polar molecule
  • Hydrogen bonds form between water molecules

    • As a result of the polarity of water hydrogen bonds form between the positive and negatively charged regions of adjacent water molecules

  • Hydrogen bonds are weak, when there are few, so they are constantly breaking and reforming

    • However when there are large numbers present they form a strong structure

  • Hydrogen bonds contribute to the many properties water molecules have that make them so important to living organisms:

    • An excellent solvent – many substances can dissolve in water

    • A relatively high specific heat capacity

    • A relatively high latent heat of vaporisation

    • Water is less dense when a solid

    • Water has high surface tension and cohesion

    • It acts as a reagent

Diagram of three water molecules showing hydrogen bonds as blue dashed lines between hydrogen and oxygen atoms, with charges indicated.
The polarity of water molecules allows hydrogen bonds to form between adjacent water molecules

Examiner Tips and Tricks

It is important to know where the hydrogen bonds form between water molecules (oxygen of one water molecule to the hydrogen atom of another).

Don't get confused with the covalent bonds between the atoms within a water molecule.

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Cara Head

Author: Cara Head

Expertise: Biology & Psychology Content Creator

Cara graduated from the University of Exeter in 2005 with a degree in Biological Sciences. She has fifteen years of experience teaching the Sciences at KS3 to KS5, and Psychology at A-Level. Cara has taught in a range of secondary schools across the South West of England before joining the team at SME. Cara is passionate about Biology and creating resources that bring the subject alive and deepen students' understanding

Alistair Marjot

Reviewer: Alistair Marjot

Expertise: Environmental Systems and Societies & Biology Content Creator

Alistair graduated from Oxford University with a degree in Biological Sciences. He has taught GCSE/IGCSE Biology, as well as Biology and Environmental Systems & Societies for the International Baccalaureate Diploma Programme. While teaching in Oxford, Alistair completed his MA Education as Head of Department for Environmental Systems & Societies. Alistair has continued to pursue his interests in ecology and environmental science, recently gaining an MSc in Wildlife Biology & Conservation with Edinburgh Napier University.