Which of these compounds would act as a nucleophile?
C2H6
H+
OH-
Al
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Electron Pair Sharing Reactions
Which of these compounds would act as a nucleophile?
C2H6
H+
OH-
Al
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Ethene reacts with steam in the presence of sulfuric acid.
C2H4 + H2O → CH3CH2OH
What type of reaction is this?
acid / base
addition
hydrolysis
substitution
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Which reaction is an example of nucleophilic substitution?
C6H6 + Br2 → C6H5Br+ HBr
CH2=CH2 + HBr → CH3CH2Br
C3H7Br + H2O → C3H7OH + HBr
C2H6 + Br2 → C2H5Br + HBr
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Bromomethane, CH3Br, is used as a fumigant to destroy insect pests in grain that is to be stored. It can be made by reacting methanol with hydrogen bromide.
CH3OH + HBr → CH3Br + H2O
What type of reaction is this?
condensation
electrophilic substitution
free radical substitution
nucleophilic substitution
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What reagents and conditions are needed to convert but-2-ene into butane?
Concentrated sulfuric acid, steam, 300oC
Hydrogen gas, Ni catalyst, 150oC
Acidified potassium dichromate, heating under reflux
Hydrogen bromide, room temperature
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Which reaction(s) can alkenes undergo?
I. Addition
II. Hydration
III. Reduction
I and II only
I and III only
II and III only
I, II and III
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In the hydrolysis of bromoethane by aqueous sodium hydroxide, what is the nature of the attacking group and of the leaving group?
| attacking group | leaving group |
A B C D | electrophile electrophile nucleophile nucleophile | electrophile nucleophile electrophile nucleophile |
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The synthesis of ethyl butanoate can be carried out in three steps:
I II III
C4H9Br → C4H9OH → C3H7COOH → C3H7COOC2H5
What is the correct classification of the steps?
| I | II | III |
A | substitution | oxidation | condensation |
B | addition | substitution | condensation |
C | oxidation | substitution | condensation |
D | substitution | oxidation | substitution |
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Which compound could be X in this two step reaction pathway?
C3H8 → X → C3H7OH
C2H5CN
C3H7Cl
C3H6Cl2
C2H5COOH
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Limonene is an oil formed in the peel of citrus fruits.
Which product is formed when an excess of bromine, Br2(l), reacts with limonene at room temperature in the dark?
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Which compound has an Mr of 84.18 and will react with HBr to give a product with an Mr of 165.09?
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Which molecule can react with both sodium borohydride, NaBH4, and warm acidified potassium dichromate(VI)?
CH3CHOHCH3
CH3C(CH3)2CHO
(CH3)3COH
CH3C(CH3)2CH2OH
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