Structure of the Atom (DP IB Physics: HL): Exam Questions

3 hours45 questions
1a4 marks

State the definition for the following terms;

i) Ionisation

[1]

ii) Photon

[1]

iii) Nuclide

[1]

iv) Isotope

[1]

1b
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6 marks

The energy of a photon can be calculated using the equation

E space equals space fraction numerator h c over denominator lambda end fraction

State the meaning of the following terms and give the unit:

(i) h

[2]

(ii) c

[2]

(iii) λ

[2]

1c
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2 marks

Calculate the wavelength of a photon with an energy of 1.44 × 10−19 J.

2a
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2 marks

Outline how the density of a nucleus varies with nuclear radius.

2b
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2 marks

Calculate the nuclear radius of carbon-14 open parentheses straight C presubscript 6 presuperscript 14 close parentheses, in m.

3
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2 marks

The density of a nucleus, ρ, is given by the equation:

rho space equals space fraction numerator 3 u over denominator 4 straight pi R subscript italic 0 to the power of italic 3 end fraction

Where u is the atomic mass unit and R0 is a constant of proportionality equal to approximately 1.20 × 10–15 m.

(i) State how the density of a nucleus changes after it undergoes radioactive decay.

[1]

(ii) Explain your answer to part (i).

[1]

4a2 marks

Describe how an emission spectra is created. 

4b4 marks

Explain the process involved in obtaining an absorption spectra. 

4c4 marks

The absorption and emission spectra for hydrogen are shown below.

structure-of-the-atom-esq2c-ib-sl-physics

State which diagram shows the emission and which is the absorption spectra and give a reason for each choice. 

4d1 mark

State how a substance can be identified by its emission line spectra. 

5a4 marks

Fluorescent tubes operate by exciting the electrons of mercury atoms.

The energy levels of a mercury atom are shown in the diagram below.

q5a_discrete-energy--radioactivity_ib-sl-physics-sq-medium

An electron is excited to the energy level n = 4.

On the diagram, draw all the possible transitions from n = 4 to the ground state n = 1.

5b
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3 marks

State and explain which energy transition will emit the photon with the lowest frequency.

6a2 marks

Rutherford's gold foil experiment involves an α particle source fired at a gold foil inside a vacuum chamber. 

Describe how air molecules can affect the experiment.

6b3 marks

The diagrams show three positions of α particles incident on a gold foil. 

Draw the complete path followed by each of the α particles shown. 

structure-of-the-atom-esq3b-ib-sl-physics
structure-of-the-atom-esq3b2-ib-sl-physics
structure-of-the-atom-esq3b3-ib-sl-physics
6c4 marks

Sketch a labelled diagram showing the experimental arrangement of the apparatus used by Rutherford.

This must include the α particle source, gold foil target and α particle detector. 

1a
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3 marks

In a HeNe laser, electrons collide with helium atoms. The ground state of a helium is labelled as 1s and the next energy level is labelled 2s.

When an electrons de-excite from 2s to 1s in helium, photons are emitted with a wavelength of 58.4 nm.

Calculate the energy difference of this transition, giving your answer in eV.

1b
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2 marks

An electron collides with a helium in its ground state, causing an electron to transition from 1s to 2s. The electron initially has 45.0 eV of kinetic energy.

Calculate the electron’s kinetic energy after the collision.

1c
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3 marks

Explain why it is not possible for the same electron from (b) to collide with the ground state helium atom and be left with 40.0 eV of kinetic energy. 

1d
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5 marks

Helium and neon coincidentally have very similar energy gaps for certain transitions, allowing one atom to cause an excitation in the other.

The excited helium atom from part (b) then collides with a ground state neon atom. The neon atom becomes excited and subsequently emits two photons in order to return to its ground state.

(i) If the helium is left back in its ground state after the collision, determine the amount of energy transferred to the neon atom.

[1]

(ii) If one photon has an energy of 1.96 eV, calculate the wavelength of the other.

[4]

2a
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3 marks

Rutherford used the scattering of α particles to provide evidence for the structure of the atom. The apparatus includes a narrow beam of α particles fired at a very thin sheet of gold foil inside a vacuum chamber.

Explain why it is essential to use:

(i) a vacuum in the chamber

[1]

(ii) a very thin sheet of gold foil    

[1]

(iii) a narrow beam of alpha particles   

[1]

2b
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3 marks

The diagram shows α particles incident on a layer of atoms in a gold foil.

On the diagram, draw the paths followed by each of the incident α particles shown.

ma1b_7-3_medium_ib-physics
2c
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5 marks

Outline the results of the scattering experiment by explaining:

(i) the main observations of the scattering experiment

[2]

(ii) the significance of each observation

[3]

2d
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6 marks

The Thomson model of the atom preceded Rutherford’s model. In the Thomson model, the atom was imagined as a sphere of positive charge of diameter 10–10 m containing electrons moving within the sphere.

Thomson’s model could explain some of the results of the Rutherford experiment, but not all.

Explain

(i) why, at small deflections, Rutherford’s experiment can be explained by Thomson’s model but not at large deflections

[3]

(ii) why Rutherford’s model of the atom can account for the results at both small and large deflections

[3]

3a
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4 marks

In the Rutherford scattering experiment, alpha particles are fired at a thin gold foil target using the experimental setup shown below.

12-2-hl-sqs-medium-q3a-question

Some of the alpha particles are backscattered.

Outline how the results of the Rutherford scattering experiment can be used to estimate the radius of a gold nucleus. Include a relevant equation.

3b
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3 marks

An alpha particle with an initial speed one-tenth that of the speed of light is fired head-on at a stationary gold nucleus open parentheses Au presubscript 79 presuperscript 197 close parentheses.

Calculate the minimum separation between the alpha particle and the centre of the gold nucleus.

3c
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4 marks

Estimate the number of nucleons in a gold nucleus based on the value of separation that you calculated in (b).

Discuss your answer in relation to:

  • the actual size of a gold nucleus

  • the accuracy of the Rutherford scattering method for determining nuclear radii.

3d
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3 marks

The target nucleus is changed to one that has fewer protons. The alpha particle is fired with the same speed as before. 

Explain, without further calculation, the effect this has on the minimum separation.

Ignore any recoil effects.

4a
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4 marks

The Bohr model was developed in order to explain the atomic spectrum of hydrogen.

Outline the Bohr model and state a limitation of it.

4b
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4 marks

The Bohr model for hydrogen can also be applied to a helium atom which has lost one of its electrons through ionisation.

The one remaining electron has a mass of m and moves in a circular orbit of radius r. Derive an expression for

(i) the kinetic energy E subscript k of the electron

[2]

(ii) the electric potential energy E subscript p

[1]

(iii) the total energy E subscript T of the atom

[1]

4c
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2 marks

Using your answer to (b), describe the predicted effect on the orbital radius of the electron when it

(i) absorbs an electromagnetic wave

[1]

(ii) emits an electromagnetic wave.

[1]

4d
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3 marks

The radius of the electron's orbit in the helium atom is 2.43 × 10−10 m.

Determine the principal quantum number of the energy level occupied by the electron.

5a
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3 marks

The lowest energy levels of an argon atom are shown below. 

structure-of-the-atom-argon-energy-levels---msq3a-ib-physics

Calculate the wavelength of an emitted photon due to the transition level n = 5 to level n = 3.

5b4 marks

Draw arrows on the diagram above to show the electron transitions which emit a photon with a longer wavelength than that emitted in the transition from n = 5 to n = 3. 

5c2 marks

A fluorescent tube is filled with argon gas at low pressure. When the argon atoms are excited, they emit photons.

Explain how the excited argon atoms emit photons.

5d3 marks

Explain how the coating on the inside surface of the glass in a fluorescent tube helps to emit photons in the visible spectrum.

1a3 marks

Two students debate which electron energy transition causes a photon of infrared radiation to be emitted from excited hydrogen atoms. 

structure-of-the-atom-hsq2a-ib-sl-physics

Student 1 thinks it’s the transition E subscript 5 to E subscript 4 .

Student 2 thinks it’s the transition E subscript 1 to E subscript 0.

State and explain which student is correct.

1b5 marks

In a new type of special effects tube covered in a special infrared absorbent coating, the hydrogen atoms inside are excited. This leads to a series of events which result in the emission of photons in the visible region of the electromagnetic spectrum from the coating of the tube. 

Describe the series of events, following the excitation of the atoms, which results in the emission of visible photons.

1c3 marks

Discuss the meaning of the first molar ionisation energy.

2a3 marks

Transitions between three energy levels in a particular atom give rise to three spectral lines. In decreasing magnitudes, these are f subscript 1, f subscript 2and f subscript 3.

The equation which relates f subscript 1, f subscript 2 and f subscript 3 is:

f subscript 1 equals f subscript 2 plus f subscript 3

Explain, including through the use of a sketch, how this equation relates f subscript 1f subscript 2 and f subscript 3.

2b
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5 marks

A different atom has a complete line emission spectra with a ground state energy of  –10.0 eV. is:

7-1-ib-sl-hard-sqs-q1b-question

Sketch and label a diagram of the possible energy levels for the atomic line spectra shown.

2c3 marks

Explain the significance of an electron at an energy level of 0 eV.

2d
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3 marks

(i) Explain the statement 'the first excitation energy of the hydrogen atom is 10.2 eV'

  [1]

(ii) The ground state of hydrogen is –13.6 eV. Calculate the speed of the slowest electron that could cause this excitation of a hydrogen atom. 

[2]

3a
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6 marks

Bohr modified the Rutherford model by introducing the condition: 

m v r space equals space n fraction numerator h over denominator 2 straight pi end fraction

The total energy En of an electron in a stable orbit is given by:

E subscript n equals negative fraction numerator k e squared over denominator 2 r end fraction

Where k equals fraction numerator 1 over denominator 4 straight pi epsilon subscript 0 end fraction

(i) Discuss one issue posed by Rutherford's model and one issue solved by Bohr's modification. 

[2]

(ii) Use Bohr's modification with the expression for total energy to derive the equation

E subscript n equals negative K over n squared

[3]

(iii) State and explain what physical quantity is represented by the constant, K

[1]

3b
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3 marks

In 1908, the physicist Friedrich Paschen first observed the photon emissions resulting from transitions from a level n to the level n = 3 of hydrogen and deduced their wavelengths were given by:

lambda space equals space fraction numerator A n squared over denominator n squared space minus space 9 end fraction

where A is a constant.

Justify this formula on the basis of the Bohr theory for hydrogen and determine an expression for the constant A.

4a
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5 marks

In a scattering experiment, a metal foil of thickness 0.4 µm scatters 1 in 20 000 alpha particles through an angle greater than 90°.

(i) Considering the metal foil as a number of layers of atoms, n, explain why the probability of an alpha particle being deflected by a given atom is approximately equal to

fraction numerator 1 over denominator 20 space 000 n end fraction

[2]

(ii) Estimate the diameter of the nucleus. Consider the nuclei as cubes and the atoms in the foil as cubes of side length 0.25 nm.

[3]

4b
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3 marks

Deviations from Rutherford scattering are observed when high-energy alpha particles are incident on nuclei.

Outline the incorrect assumption used in the Rutherford scattering formula and suggest an explanation for the observed deviations.

4c
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3 marks

In a scattering experiment, alpha particles were directed at five different thin metallic foils, as shown in the table. 

Metal

Symbol

Silver

Ag presubscript 47 presuperscript 108

Aluminium

Al presubscript 13 presuperscript 27

Gold

Au presubscript 79 presuperscript 197

Tin

Sn presubscript 50 presuperscript 119

Tungsten

straight W presubscript 74 presuperscript 184

Initially, all alpha particles have the same energy. This energy is gradually increased. 

Predict and explain the differences in deviations from Rutherford scattering that will be observed.

4d
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3 marks

Outline why the particles must be accelerated to high energies in scattering experiments. 

5
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3 marks

The isotope beryllium-10 is formed when a nucleus of deuterium open parentheses straight H presubscript 1 presuperscript 2 close parentheses collides with a nucleus of beryllium-9 open parentheses Be presubscript 4 presuperscript 9 close parentheses. The radius of a deuterium nucleus is 1.5 fm. 

(i) Determine the minimum initial kinetic energy, in J, that the deuterium nucleus must have in order to produce the isotope beryllium-10.

[2]

(ii) Outline an assumption made in this calculation.

[1]

6
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3 marks

Show that all nuclei have the same density.