Physical Properties of the Group 17 Elements (Cambridge (CIE) A Level Chemistry): Exam Questions

Exam code: 9701

37 mins14 questions
1a
4 marks

The elements of Group 17 of the Periodic Table show trends in their properties.

i) Complete Table 2.1, stating the colour of each element in its state at room temperature.

[2] 

Table 2.1

Halogen

Boiling point / °C

Colour

Chlorine

-36

 

Bromine 

59

 

Iodine 

184 

 

ii) Briefly explain why the boiling points of the halogens increase from chlorine to iodine.

[2]

1b
1 mark

State the full electronic configuration for bromine.

1c
3 marks

Explain why bromine is a liquid at room temperature, but fluorine and chlorine are gases.

1d
3 marks

The bond enthalpy of the halogen molecules generally decreases down Group 17. Explain why the bond strength of fluorine is lower than that of chlorine. 

2a
3 marks

Chlorine is a greenish-yellow gas, bromine is a dark red liquid, and iodine is a dark grey solid.

State and explain the property which most directly causes these differences in volatility.

2b
2 marks

Explain why Cl2 rather than Br2 would react more vigorously with a solution of I-.

2c
2 marks

Astatine, At, is the rarest naturally occurring element in the Earth’s crust. Before it was discovered in 1940 scientists could only predict its existence and properties.

Suggest the basis for these predictions.

3a
4 marks

State and explain the trend in the boiling points of the halogens from fluorine to iodine.

trend 

explanation 

3b
2 marks

The bond enthalpies of the halogens generally decrease down the group as shown in Table 3.1. 

Table 3.1 

Halogen

Bond enthalpy (kJ mol–1)

F–F

159

Cl–Cl

242

Br–Br

193

I–I

151

State and explain the deviation in this trend.

deviation

explanation

3c
2 marks

Chlorine is a strong oxidising agent.

Write the simplest ionic equation for the reaction between chlorine and aqueous sodium iodide. State what is observed when this reaction occurs.

equation

observation