Organic Synthesis (Edexcel International A Level (IAL) Chemistry): Exam Questions

Exam code: YCH11

18 mins7 questions
1a
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3 marks

Ketones are useful starting compounds in organic synthesis.

This question is about butanone.

q20-paper-5-jan-2021-edexcel-ial-chemistry

The mass spectrum of butanone has significant peaks at m/ z = 43 and at m/ z = 57.

i) Give the structures of the species responsible for these two peaks.

(2)

ii) Give the structure of one other species that you would expect to produce a peak at a different m/ z value in the mass spectrum of butanone.

(1)

1b
4 marks

Devise a reaction scheme to prepare propan-1-ol from butanone, using no more than four steps.

Identify the reagents and essential conditions for each step and give the name or structure of each of the intermediate compounds.

1c
5 marks

Devise a reaction scheme to prepare 2-methylbut-2-ene from butanone, using no more than four steps.

Identify the reagents and essential conditions for each step and give the name or structure of each of the intermediate compounds.