Wave-Particle Duality (AQA A Level Physics): Flashcards

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  • Define corpuscular theory.

Cards in this collection (81)

  • Define corpuscular theory.

    Corpuscular theory is Newton's theory that light is made of small particle-like bodies called corpuscles, emitted by luminous objects.

  • How did corpuscular theory explain reflection?

    Corpuscles hit the reflective surface and experienced an equal and opposite repulsive force, following Newton's third law, as corpuscular theory treated corpuscles like solid, elastic spheres.

  • According to corpuscular theory, why does light change direction at a boundary between air and a denser medium?

    A resultant force acts on the corpuscles perpendicular to the boundary, due to a greater attraction from the increased matter in the denser medium, which increases the vertical component of the corpuscle's velocity.

  • Define wavefront.

    A wavefront is emitted from a point source, and every point on it acts as a secondary point source producing wavelets, which join together to form the next wavefront.

  • Why did Huygens propose the existence of the "luminiferous aether"?

    All other known waves needed a medium to travel through, so Huygens suggested a massless medium filled the Universe for light waves to travel through.

  • Name properties of light that corpuscular theory could and could not explain.

    Corpuscular theory could explain reflection, refraction and dispersion, but had no explanation for diffraction or interference.

  • Corpuscular theory predicted light travelled .......... in a denser medium, while wave theory predicted light travelled .......... in a denser medium.

    Corpuscular theory predicted light travelled faster in a denser medium, while wave theory predicted light travelled slower in a denser medium.

  • True or False?

    Newton's corpuscular theory was rejected as soon as Huygens proposed his wave theory.

    False.

    Corpuscular theory remained the accepted theory of light for about 150 years, largely due to Newton's reputation and the lack of any way to measure the speed of light or observe diffraction at the time.

  • Why did Young use a monochromatic light source in his double-slit experiment?

    To ensure the two rays produced from the slits were coherent.

  • Define interference pattern.

    A pattern of alternating bright and dark fringes produced on a screen where light from two coherent sources overlaps.

  • What pattern did Newton's corpuscular theory predict for the double-slit experiment, and why?

    It predicted only two bright regions on the screen, since corpuscular theory treats light as particles travelling in straight lines through each slit, like paintballs fired through two gaps.

  • What causes the bright and dark fringes in Young's interference pattern?

    Bright fringes form where the two coherent sources constructively interfere; dark fringes form where they destructively interfere.

  • Why was Young's double-slit experiment strong evidence for the wave theory of light?

    The interference pattern could only be explained if light diffracted through the slits like a wave, a phenomenon corpuscular theory could not account for.

  • The interference pattern on the screen occurred because light .......... through the thin slits, behaving like a ...........

    The interference pattern on the screen occurred because light diffracted through the thin slits, behaving like a wave.

  • True or False?

    Young's double-slit experiment alone was enough to make the scientific community immediately accept the wave theory of light.

    False.

    Although it was definite evidence for wave theory, corpuscular theory was not immediately rejected; further experiments, most importantly Fizeau's measurement of the speed of light in water, were needed before wave theory became accepted.

  • Define electromagnetic wave.

    A wave of oscillating electric and magnetic fields, perpendicular to each other, which propagate each other without needing a medium.

  • How does an accelerating charged particle produce an electromagnetic wave?

    The accelerating charge produces an alternating electric field perpendicular to its motion; this produces a perpendicular alternating magnetic field, which in turn regenerates the electric field, and so on (self-propagation).

  • Why can light travel through a vacuum, unlike other waves?

    Because the alternating electric and magnetic fields self-propagate each other, so no physical medium is needed.

  • Define permittivity of free space, ε0.

    A constant that relates electric field strength to the charged object in free space producing the field.

  • Define permeability of free space, μ0.

    A constant that relates magnetic flux density to the current in free space that produces the field.

  • State Maxwell's equation for the speed of electromagnetic waves in a vacuum, c.

    c = \frac{1}{\sqrt{\mu_{0} \epsilon_{0}}}

  • Since μ0 and ε0 are both .........., Maxwell's equation shows the speed of electromagnetic waves in a vacuum is also ...........

    Since μ0 and ε0 are both constant, Maxwell's equation shows the speed of electromagnetic waves in a vacuum is also constant.

  • True or False?

    In an electromagnetic wave, the electric and magnetic fields oscillate in the same plane as each other.

    False.

    The electric field's oscillation is perpendicular to the magnetic field's oscillation.

  • Define Hertz's radio wave transmitter.

    A short air gap between wires, across which a large potential difference produced high-voltage sparks that generated radio waves.

  • Describe the two detectors Hertz used to detect radio waves.

    A circular wire with a small break, which produced sparks across the break, and a concave metal sheet with two parallel metal rods at its centre, across which an oscillating potential difference was induced.

  • How did Hertz demonstrate that radio waves could be reflected?

    He placed a metal screen behind the source and measured a stronger signal with the detector, showing some radio waves had reflected off the screen back towards the detector.

  • How did Hertz demonstrate that radio waves were polarised?

    When the detector was rotated 90° perpendicular to the path of the radio waves, sparks stopped being produced, showing the waves' magnetic fields oscillated in only a single plane.

  • Describe how Hertz measured the speed of radio waves.

    He reflected radio waves off a flat metal sheet to produce a standing wave, then passed a detector across it: strong signals occurred at antinodes and none at nodes. This gave the wavelength, which combined with the transmitter's known frequency using v = fλ gave the speed.

  • Why was Hertz's measurement of the speed of radio waves significant?

    The value he obtained was very close to the speed of electromagnetic waves calculated by Maxwell, showing that radio waves are electromagnetic waves.

  • When an insulator was placed between the transmitter and detector, there was .......... in the signal detected, showing radio waves could .......... insulators.

    When an insulator was placed between the transmitter and detector, there was no difference in the signal detected, showing radio waves could penetrate insulators.

  • True or False?

    The distance between adjacent antinodes in Hertz's standing wave was equal to one full wavelength of the radio wave.

    False.

    The distance between adjacent antinodes is equal to half the wavelength of the wave.

  • Define the toothed wheel used in Fizeau's experiment.

    A rapidly spinning wheel with alternating teeth and gaps, placed in the path of a light beam, which periodically blocked or transmitted the light to create regular pulses.

  • In Fizeau's experiment, what did the observer see when the returning light hit the tooth next to the original gap it passed through?

    No light returning from the mirror; the returning light was blocked by the tooth.

  • State Fizeau's final equation for the speed of light, c, in terms of the wheel distance d, number of gaps n, and rotational frequency f.

    c = 4 d n f

  • What did Fizeau find when he compared the speed of light in water and in air?

    The speed of light in water was slower than in air.

  • How did Fizeau's result for the speed of light in water contradict Newton's corpuscular theory?

    Corpuscular theory predicted light would travel faster in a denser medium, but Fizeau found light travelled slower in water than in air.

  • The total path length of light in Fizeau's experiment was .........., from the source to the mirror and back to the observer.

    The total path length of light in Fizeau's experiment was 2*d*, from the source to the mirror and back to the observer.

  • True or False?

    Before Fizeau's experiment, some scientists believed light travelled at an infinite speed.

    True.

    Scientists used to believe light covered distance instantaneously, though some astronomical observations had already contradicted this before Fizeau measured a finite speed.

  • Define a black body.

    A theoretical object that absorbs all radiation incident on it and does not reflect or transmit any radiation.

  • How does the wavelength of peak intensity in a black-body's emission spectrum change as its temperature increases?

    The wavelength of peak intensity decreases (shifts to shorter wavelengths) as temperature increases.

  • What was the "ultra-violet catastrophe"?

    The disagreement between experimentally measured black-body spectra and the spectra predicted by classical wave theory, which predicted an infinite amount of ultra-violet radiation would be emitted as temperature increased.

  • Why did classical wave theory fail to correctly predict black-body radiation spectra?

    Classical theory treated electromagnetic radiation purely as a wave, which predicted an infinite emission of ultra-violet radiation as temperature increased, in stark disagreement with experimental data.

  • Define quantised energy.

    Energy that can only be emitted or absorbed in discrete integer multiples of a fixed packet size, rather than continuously.

  • State Planck's equation for the energy emitted by an oscillator of frequency f.

    E = n h f

    where n is an integer and h is Planck's constant (6.63 × 10-34 J s).

  • Planck assumed oscillators could only emit energy in .......... multiples of packets, or .........., of energy.

    Planck assumed oscillators could only emit energy in integer multiples of packets, or quanta, of energy.

  • True or False?

    A cube of metal at room temperature emits mostly visible light.

    False.

    At room temperature, the metal cube emits invisible infrared radiation; it only emits significant visible light, glowing red, orange or white, once heated to around 3000 K.

  • Define photon.

    A photon is a discrete packet (quantum) of electromagnetic energy, of size E = hf, which Einstein proposed was massless.

  • What did wave theory predict would happen if low-frequency radiation was shone on a metal at high intensity for long enough?

    Wave theory predicted photoelectrons would eventually be emitted, because energy is transferred continuously and would build up over time until enough had been transferred to remove electrons.

  • According to photon theory, why does radiation below the threshold frequency never cause photoelectric emission, no matter how intense it is?

    Each photon transfers all its energy to only one electron. If hf is too small to remove an electron, photons cannot combine their energy, so increasing intensity (the number of photons) has no effect.

  • Why does increasing the frequency of incident radiation increase the kinetic energy of emitted photoelectrons?

    Each photon transfers all its energy hf to one electron. Any energy above that needed to remove the electron becomes kinetic energy, so a larger hf leaves more energy for the electron.

  • According to wave theory, an electromagnetic wave transfers energy .........., rather than in discrete packets.

    According to wave theory, an electromagnetic wave transfers energy continuously, rather than in discrete packets.

  • True or False?

    Increasing the intensity of radiation above the threshold frequency increases the kinetic energy of the emitted photoelectrons.

    False.

    Increasing intensity only increases the number of photons, and so the number of photoelectrons emitted. The kinetic energy of each photoelectron depends only on the frequency of the radiation.

  • Who provided the theoretical explanation of the photoelectric effect, and whose earlier work did it build on?

    Einstein explained the photoelectric effect in 1905, building on Max Planck's work on black-body radiation.

  • Define De Broglie wavelength.

    The De Broglie wavelength is the wavelength associated with a moving particle, given by \lambda = \frac{h}{p} where h is Planck's constant and p is the particle's momentum.

  • How did De Broglie derive an equation for the momentum of a photon?

    By equating Einstein's mass-energy equation E=mc^2 with the photon energy equation E=hf, giving mc=\frac{h}{\lambda}, so a photon's momentum is p=\frac{h}{\lambda}.

  • What equation gives the De Broglie wavelength of an electron accelerated through potential difference V?

    \lambda = \frac{h}{\sqrt{2meV}} where m is the electron's mass and e is its charge.

  • What happens to an electron's De Broglie wavelength as it is accelerated to a higher speed?

    Its De Broglie wavelength decreases.

  • De Broglie hypothesised that all particles can behave both like .......... and like particles.

    De Broglie hypothesised that all particles can behave both like waves and like particles.

  • True or False?

    Doubling the accelerating potential difference across an electron halves its De Broglie wavelength.

    False.

    Since \lambda \propto \frac{1}{\sqrt{V}}, doubling V only reduces the wavelength by a factor of \sqrt{2}, not by half.

  • Which relationship lets you find an accelerated electron's speed before calculating its De Broglie wavelength?

    The work done on the electron by the electric field equals its kinetic energy: eV = \frac{1}{2}mv^{2}.

  • Define electron diffraction.

    Electron diffraction is the spreading out of an electron beam as it passes through small gaps (such as those between atoms in a thin graphite film), producing a circular pattern on a fluorescent screen — direct evidence of electrons' wave-like properties.

  • In the electron diffraction experiment, what happens to the diffraction pattern as the accelerating potential difference is increased, and why?

    The diffraction rings move closer to the centre of the screen. Increasing the potential difference increases electron speed, decreasing the De Broglie wavelength, which decreases the diffraction angle for a given gap width.

  • What material was used as the diffracting target in the electron diffraction experiment, and why was it suitable?

    A thin film of graphite; the gaps between its carbon atoms were small enough to diffract electrons of the De Broglie wavelength produced.

  • Why does a microscope using shorter-wavelength radiation have a greater resolving power?

    A shorter wavelength allows the microscope to distinguish two points on an object that are closer together, revealing finer detail.

  • Why do researchers want to know the anode voltage needed to give electrons a wavelength similar to the size of an atom (around 10-10 m)?

    At this wavelength, an electron beam's resolving power becomes fine enough to distinguish individual atoms, so this voltage sets a target for imaging atomic-scale structure.

  • Diffraction is a property of .......... when passing through a small gap.

    Diffraction is a property of waves when passing through a small gap.

  • True or False?

    The circular pattern in the electron diffraction experiment is produced by electrons behaving as particles that scatter off individual carbon atoms.

    False.

    The pattern is produced by electrons behaving as waves, diffracting through the gaps between carbon atoms, not by particle scattering.

  • Define transmission electron microscope (TEM).

    A TEM is a microscope that focuses a beam of electrons using magnetic lenses; the electrons pass through a thin sample and form an image on a fluorescent screen.

  • What is the function of the condenser lens in a TEM?

    It deflects electrons from the electron gun into a wide beam travelling parallel to the microscope's axis, so the beam is incident uniformly on the sample.

  • What is the function of the objective lens in a TEM?

    It forms an image of the sample by deflecting the outer electrons of the beam towards the central axis, similar to how a convex lens focuses light.

  • What is the function of the projector lens in a TEM?

    It spreads out the beam from the objective lens, magnifying the image and directing it onto a fluorescent screen.

  • Why does passing electrons through the sample reduce a TEM's resolving power below what its wavelength alone would allow?

    Passing through the sample slows the electrons, increasing their De Broglie wavelength and reducing resolving power. Electrons are also slowed by differing amounts, giving them a range of speeds and producing a blurrier image.

  • Electrons are emitted from the electron gun of a TEM by .........., then accelerated to high speed by a large potential difference.

    Electrons are emitted from the electron gun of a TEM by thermionic emission, then accelerated to high speed by a large potential difference.

  • True or False?

    All electrons passing through the sample in a TEM travel at the same speed, producing a perfectly sharp image.

    False.

    Not all electrons are slowed by the sample to the same degree, so they have a range of speeds and are deflected by different amounts in the magnetic lenses, producing a blurrier image.

  • Define quantum tunnelling.

    Quantum tunnelling is the process by which electrons, because of their wave-like nature, cross a narrow barrier (such as a small gap) that they could not cross classically, since their matter-wave amplitude is reduced but not zero on the far side of the barrier.

  • What is a piezoelectric transducer used for in an STM?

    It moves the probe tip in tiny increments (as small as 0.001 nm) in any direction.

  • Why does the tunnelling current increase when the STM tip passes over a raised atom?

    The gap between the tip and the surface decreases, so more electrons tunnel across it, increasing the tunnelling current.

  • What is the difference between constant height mode and constant current mode in an STM?

    In constant height mode, the tip stays at a fixed height and the tunnelling current varies with the surface, producing the image. In constant current mode, the tip moves up and down to keep the current (and gap size) constant, and this vertical motion produces the image.

  • Under what condition does quantum tunnelling occur across the gap in an STM?

    Only when the barrier (gap) is weak enough, i.e. the distance between tip and surface is small enough, for the electron's matter-wave amplitude to remain non-zero on the far side.

  • An STM's probe tip is held a few .......... above the surface of the sample.

    An STM's probe tip is held a few nanometres above the surface of the sample.

  • True or False?

    In an STM, electrons travel directly across the gap between the sample and the tip as free particles, obeying classical physics.

    False.

    Electrons cross the gap by quantum tunnelling, a wave-like effect not permitted by classical physics; classically the electrons would not have enough energy to cross the barrier.

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