Exam code: 8464
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Define element.
An element is a pure substance that consists of only one type of atom, distinguished by its unique number of protons.

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Define element.
An element is a pure substance that consists of only one type of atom, distinguished by its unique number of protons.
What does the atomic number (Z) of an element tell you?
The atomic number (Z) is the number of protons in the nucleus of an atom. It is unique to each element and is always the smaller of the two numbers shown with a chemical symbol.
In a two-letter chemical symbol, the first letter is always ________ and the second is always ________.
In a two-letter chemical symbol, the first letter is always uppercase and the second is always lowercase.
True or False?
The mass number is always the smaller of the two numbers shown with a chemical symbol.
False.
The atomic number is the smaller number (number of protons only). The mass number is the larger number (protons + neutrons).
What is an atom?
An atom is the smallest particle of an element that retains the properties of that element. It consists of a nucleus containing protons and neutrons, surrounded by electrons moving in shells.
Why must you write Cl2 rather than Cl when representing chlorine in a chemical equation?
Chlorine exists naturally as a diatomic molecule, meaning two atoms are bonded together. Writing Cl would imply a single atom, which does not exist under normal conditions, making the equation chemically incorrect.
Complete the list of diatomic elements: H2, ________ O2, ________, Cl2, and I2.
The complete list of diatomic elements is H2, N2, O2, F2, Cl2, Br2 and I2.
Which elements in the Periodic Table must you know the names and symbols for?
You must know the names and symbols for the first 20 elements, plus all elements in Group 1 and Group 7.
Define compound.
A compound is a substance formed when two or more elements are chemically bonded together in fixed proportions.
What information does the formula NH3 give you?
The formula NH3 tells you that each molecule of ammonia contains one nitrogen atom and three hydrogen atoms chemically bonded together.
Complete the rule: when naming ionic compounds, the ________ comes first and the non-metal ends in ________.
The metal comes first and the non-metal ends in -ide (e.g. sodium chloride, magnesium oxide).
True or False?
A compound has the same properties as the elements it is made from.
False.
A compound has different properties from the elements it contains because the atoms are chemically combined in a new structure.
Complete the table of common compound formulas:
Compound | Formula |
|---|---|
Water | |
Ammonia | |
Methane | |
Hydrochloric acid |
Compound | Formula |
|---|---|
Water | H2O |
Ammonia | NH3 |
Methane | CH4 |
Hydrochloric acid | HCl |
How do you work out the formula of an ionic compound from the charges of its ions?
Find the charges of each ion, then use the smallest whole-number ratio that makes the overall charge zero. For example, Mg²⁺ and Cl⁻ combine as MgCl2 because two Cl⁻ ions are needed to balance one Mg²⁺ ion.
Define word equation.
A word equation shows a chemical reaction using the full names of reactants and products, written as:
reactants → products.
In a chemical equation, which side of the arrow contains the reactants and which contains the products?
Reactants appear on the left-hand side of the arrow; products appear on the right. The arrow, spoken as "to form" or "produces", represents the conversion of reactants into products.
A symbol equation is balanced when the number of ________ of each element is the same on both sides of the equation.
A symbol equation is balanced when the number of atoms of each element is the same on both sides of the equation.
True or False?
To balance a symbol equation, you can change the small subscript numbers inside chemical formulae.
False.
Changing the subscripts changes the substance itself. To balance an equation, change only the large coefficients written in front of the formulae.
Complete the state symbols table:
State | Symbol |
|---|---|
Solid | |
Liquid | |
Gas | |
Aqueous |
State | Symbol |
|---|---|
Solid | (s) |
Liquid | (l) |
Gas | (g) |
Aqueous | (aq) |
What type of information can be written above the arrow in a chemical equation?
Reaction conditions (such as temperature or pressure) or the name of a catalyst can be written above the arrow.
True or False?
The state symbol for a gas can be written as "gas" or "(G)" as well as "(g)".
False.
State symbols must always be lowercase and enclosed in brackets. Writing the full word ("gas") or using upper case ("(G)") will not be credited in exams. The four state symbols are: (s), (l), (g) and (aq).
Define half equation.
A half equation shows what happens to one species during a redox reaction, including balanced atoms, balanced charges, and the gain or loss of electrons.
What does the mnemonic OIL RIG stand for in terms of electron transfer?
OIL RIG: Oxidation Is Loss of electrons; Reduction Is Gain of electrons.
In a half equation, electrons on the ________ show the species is gaining electrons (reduction), and electrons on the ________ show it is losing electrons (oxidation).
In a half equation, electrons on the left show the species is gaining electrons (reduction), and electrons on the right show it is losing electrons (oxidation).
What is an ionic equation?
An ionic equation shows only the particles that change during a reaction.
Spectator ions (those present but unchanged) are cancelled from both sides.
True or False?
In an ionic equation, all compounds (including solids and gases) are split into their ions.
False.
Only aqueous compounds are split into ions. Solids, liquids and gases remain in their molecular form.
Write the half equation for the reduction of copper(II) ions to copper metal.
Copper(II) ions gain two electrons to form neutral copper atoms:
Cu²⁺ + 2e⁻ → Cu
Electrons are on the left, confirming this is reduction.
Why must electrons be written as e⁻ in a half equation, not just e?
The negative charge (⁻) must be shown because it is essential for balancing the charges on both sides of the half equation. Writing e without the charge will not be credited in exams.
True or False?
The ionic equation for the neutralisation of any acid with any alkali can be written as:
acid + alkali → salt + water.
False.
The ionic equation is:
H+ (aq) + OH- (aq) → H2O (l).
Spectator ions are cancelled, leaving only the hydrogen and hydroxide ions combining to form water. The general word description is not an ionic equation.
Define mixture.
A mixture contains two or more substances that are not chemically joined together. Mixtures can be separated by physical processes such as filtration, distillation, evaporation and chromatography.
What type of mixture does filtration separate, and what are the names of the two fractions collected?
Filtration separates an insoluble solid from a liquid or solution.
The liquid that passes through is the filtrate; the solid that remains is the residue.
Crystallisation separates a ________ solid from a solution. After heating to evaporate the solvent, the saturated solution is cooled slowly so that ________ form.
Crystallisation separates a dissolved solid from a solution. After heating to evaporate the solvent, the saturated solution is cooled slowly so that crystals form.
True or False?
Simple distillation is the best method for separating two liquids with similar boiling points.
False.
Fractional distillation is used when liquids have similar boiling points.
Simple distillation is used to separate a liquid from a dissolved solid, or when the boiling points differ significantly.
Why can mixtures be separated by physical methods, but compounds cannot?
In a mixture, substances are not chemically bonded, so no bonds need to be broken to separate them. Physical processes exploit differences in properties such as boiling point, solubility or particle size.
Fractional distillation separates miscible liquids by exploiting differences in ________. The liquid with the ________ boiling point evaporates and is collected first.
Fractional distillation separates miscible liquids by exploiting differences in boiling point. The liquid with the lowest boiling point evaporates and is collected first.
In paper chromatography, why must the baseline be drawn in pencil, and the solvent level stay below the baseline?
Ink would dissolve in the solvent and run with the sample, contaminating the chromatogram.
If the solvent covers the spots, the sample will dissolve directly into it rather than travelling up the paper by capillary action.
True or False?
In crystallisation, you should heat the solution until all the water has evaporated and the dish is completely dry.
False.
You should heat the solution to partially evaporate the solvent until a saturated solution forms, then leave it to cool slowly so crystals form. Heating to dryness damages the crystals and is not accepted in exams.
Why do different substances travel different distances up the paper in paper chromatography?
Different substances have different solubilities in the solvent and different attractions for the paper. More soluble substances travel further; less soluble substances are held back by the paper.
Describe the plum pudding model.
The plum pudding model, proposed by J.J. Thomson after his discovery of the electron in 1897, described the atom as a sphere of positive charge with negatively charged electrons embedded throughout it.
In Rutherford's gold foil experiment, what did he expect to observe, and what did he actually find?
He expected all alpha particles to pass straight through (based on the plum pudding model). Instead, most passed through, some were deflected, and a small number bounced straight back.
Rutherford concluded that atoms are mostly ________ space, with a tiny, dense, positively charged ________ at the centre.
Rutherford concluded that atoms are mostly empty space, with a tiny, dense, positively charged nucleus at the centre.
True or False?
Scientific models of the atom have remained unchanged since they were first proposed.
False.
Models are updated when new experimental evidence is found. The atomic model changed from solid sphere (Dalton) to plum pudding (Thomson) to nuclear (Rutherford) to shells (Bohr) as new discoveries were made.
What key improvement did Niels Bohr make to Rutherford's nuclear model?
Bohr proposed that electrons orbit the nucleus in fixed shells (energy levels) at specific distances from the nucleus. This explained why electrons do not spiral into the nucleus.
Complete the table of atomic model contributions:
Scientist | Key contribution |
|---|---|
Thomson | |
Rutherford | |
Bohr | |
Chadwick |
Scientist | Key contribution |
|---|---|
Thomson | Discovered electron; proposed plum pudding model |
Rutherford | Gold foil experiment; nuclear model (empty space + nucleus) |
Bohr | Electrons orbit nucleus in fixed shells |
Chadwick | Discovered neutron (1932) |
What did James Chadwick discover in 1932, and why was it important?
Chadwick discovered the neutron, a neutral particle in the nucleus. This explained the mass of atoms, which could not be accounted for by protons and electrons alone.
Why are some alpha particles deflected when fired at gold foil in Rutherford's experiment?
The nucleus is positively charged. Positive alpha particles passing close to the nucleus are repelled by the positive charge, causing deflection. A small number bounce straight back because they hit the nucleus almost head-on.
Complete the table of subatomic particle charges:
Particle | Relative charge |
|---|---|
Proton | |
Neutron | |
Electron |
Particle | Relative charge |
|---|---|
Proton | +1 |
Neutron | 0 |
Electron | −1 |
Why is an atom electrically neutral overall, even though it contains charged particles?
Atoms contain equal numbers of protons (+1) and electrons (−1), so the positive and negative charges cancel out.
True or False?
A proton has a negative charge.
False.
A proton has a relative charge of +1 (positive). A neutron is neutral (charge = 0) and an electron has a relative charge of −1.
How can you remember the charges of a proton and neutron?
Protons are Positive.
Neutrons are Neutral.
This leaves electrons as the negatively charged subatomic particle.
A neutral atom contains 15 protons. How many electrons does it contain, and why?
It contains 15 electrons. In a neutral atom, the number of electrons must equal the number of protons so that the charges cancel and the overall charge is zero.
Define isotopes.
Isotopes are atoms of the same element that have the same number of protons (and electrons) but different numbers of neutrons. They have the same chemical properties because they have the same electron configuration.
Complete the relative mass table:
Particle | Relative mass |
|---|---|
Proton | |
Neutron | |
Electron |
Particle | Relative mass |
|---|---|
Proton | 1 |
Neutron | 1 |
Electron | very small (~1/1840 of a proton) |
What is the difference between atomic number (Z) and mass number (A)?
The atomic number (Z) is the number of protons in the nucleus; the mass number (A) is the total number of protons and neutrons. The number of neutrons = A − Z.
True or False?
Isotopes of the same element have different chemical properties because they contain different numbers of neutrons.
False.
Isotopes have the same chemical properties because they have the same number of electrons in their outer shells. Neutrons are neutral and only add mass.
An atom of sodium has atomic number 11 and mass number 23. How many protons, electrons and neutrons does it have?
Protons = 11 (= atomic number).
Electrons = 11 (neutral atom).
Neutrons = 23 − 11 = 12 (mass number − atomic number).
Where is virtually all of an atom's mass concentrated, and why?
Almost all mass is in the nucleus, which contains protons and neutrons (relative mass = 1 each). Electrons have a very small mass (~1/1840 of a proton) and orbit the nucleus in shells.
True or False?
On the periodic table, the atomic number is always the larger of the two numbers shown with an element symbol.
False.
The mass number is always the larger number. Think: MASS = MASSIVE. The smaller number is the atomic (proton) number.
A fluoride ion (F⁻) has atomic number 9 and mass number 19. How many protons, electrons and neutrons does it have?
Protons = 9.
Electrons = 9 + 1 = 10 (gained 1 electron due to the 1− charge).
Neutrons = 19 − 9 = 10 (mass number − atomic number).
Define relative atomic mass (Ar).
The relative atomic mass (Ar) is the average mass of an atom of an element, accounting for the abundance of its isotopes, relative to 1/12 the mass of a carbon-12 atom. It has no units because it is a ratio.
Why does relative atomic mass (Ar) have no units?
Ar is a ratio that compares the average mass of an atom to 1/12 the mass of a carbon-12 atom. Since it compares two masses, the units cancel out.
True or False?
The relative atomic mass of an element is always a whole number.
False.
Ar is a weighted average across all isotopes of an element. Since elements exist as a mix of isotopes, Ar can be a decimal (e.g. chlorine has Ar = 35.5).
The relative atomic mass is calculated as: the ________ of (% abundance × mass of each isotope), divided by ________.
The relative atomic mass is calculated as: the sum of (% abundance × mass of each isotope), divided by 100.
Chlorine exists as 75% Cl-35 and 25% Cl-37. Calculate its relative atomic mass.
Ar = [(75 × 35) + (25 × 37)] ÷ 100 = (2625 + 925) ÷ 100 = 35.5
Complete the table showing the maximum number of electrons in each electron shell:
Shell | Max electrons |
|---|---|
1st | |
2nd | |
3rd |
Shell | Max electrons |
|---|---|
1st | 2 |
2nd | 8 |
3rd | 8 |
An element has the electronic configuration 2,8,5. What period and group of the periodic table does it belong to?
Period 3, Group 5.
The number of electron shells gives the period (3 shells = Period 3) and the number of outer-shell electrons gives the group (5 outer electrons = Group 5).
True or False?
Elements in the same group of the periodic table have the same number of electrons in their outer shell.
True.
Elements in the same group have the same number of outer-shell electrons, which is why they have similar chemical properties.
Complete the electronic configurations:
Na (Z = 11):
Cl (Z = 17):
Na (Z = 11): 2,8,1
Cl (Z = 17): 2,8,7
What is the electronic configuration of potassium (K, Z = 19)?
2,8,8,1.
Potassium requires a fourth electron shell because the third shell is full at 8 electrons, leaving 1 electron in the fourth shell.
What is the electronic configuration of a sodium ion (Na⁺)?
2,8.
Sodium loses its one outer-shell electron to form Na⁺, giving it the same electronic configuration as neon.
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