Relative Atomic Mass & Relative Molecular Mass (WJEC GCSE Science (Double Award): Chemistry): Revision Note

Exam code: 3430

Alexandra Brennan

Written by: Alexandra Brennan

Reviewed by: Caroline Carroll

Updated on

Ar & Mr

Relative Atomic Mass

  • The symbol for relative atomic mass is Ar

  • The relative atomic mass for each element can be found in the Periodic Table, along with the atomic number

    • Relative atomic mass is shown above the atomic symbol

    • It is always larger than the atomic number (except for hydrogen, where they are the same)

Key for chemical symbols on the Periodic Table

FAoIXG6n_chemical-symbol-key

This key is given on the Periodic Table in exams and shows that the top number is the relative atomic mass.

  • Atoms are too small to accurately weigh but scientists needed a way to compare the masses of atoms 

    • Carbon-12 is used as the standard atom and has a fixed mass of 12 units 

    • The mass of all other atoms are compared against carbon-12 

  • The relative atomic mass of carbon is 12

    • The relative atomic mass of magnesium is 24 which means that magnesium is twice as heavy as carbon 

    • The relative atomic mass of hydrogen is 1 which means it has one-twelfth the mass of one carbon-12 atom 

Examiner Tips and Tricks

  • Relative atomic mass (Ar) is the average mass of the isotopes of an element compared to 1/12th of the mass of an atom of 12

  • You are not required to know this definition but it can help with your understanding 

Relative molecular (formula) mass

  • The symbol for the relative molecular mass is Mr and it refers to the total mass of the molecule

  • To calculate the Mr of a substance, you have to add up the relative atomic masses of all the atoms present in the formula

  • Relative formula mass is used when referring to the total mass of an ionic compound

Relative Formula Mass Calculations Table

Substance

Atoms present

Calculation

Mr 

Hydrogen H2 

2 x H

(2 x 1)

2

Water H2O

(2 x H) + (1 x O)

(2 x 1) + (1 x 16)

18

Potassium carbonate K2CO3 

(2 x K) + (1 x C) + (3 x O)

(2 x 39) + (1 x 12) + (3 x 16)

138

Calcium hydroxide Ca(OH)2 

(1 x Ca) + (2 x O) + (2 x H)

(1 x 40) + (2 x 16) + (2 x 1)

74

Ammonium sulfate (NH4)2SO4

(2 x N) + (8 x H) + (1 x S) + (4 x O)

(2 x 14) + (8 x 1) + (1 x 32) + (4 x 16)

132

Worked Example

Calculate the relative formula mass of:

  1. Sodium chloride, NaCl

  2. Copper oxide, CuO

  3. Magnesium nitrate, Mg(NO3)2

Answers:

  1. Sodium chloride

    • NaCl = 23 + 35.5 = 58.5

  2. Copper oxide

    • CuO = 63.5 + 16 = 79.5

  3. Magnesium nitrate

    • Mg(NO3)2 = 24 + (14 x 1 x 2) + (16 x 3 x 2) = 148

Higher tier

  • Mass number is the sum of protons and neutrons present in the nucleus

    • Mass number is a whole number value

  • Relative atomic mass is the ratio of the mass of an element compared to 1/12th of the mass of a carbon atom

    • Relative atomic mass can be a decimal 

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Alexandra Brennan

Author: Alexandra Brennan

Expertise: Chemistry Content Creator / Senior Marketing Executive

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.

Caroline Carroll

Reviewer: Caroline Carroll

Expertise: Head of Content Delivery

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about delivering high-quality resources to help students achieve their full potential.