Chemical tests (Edexcel IGCSE Chemistry (Modular): Unit 2): Flashcards

Exam code: 4XCH1

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  • Complete the table of tests for gases.

    Gas

    Test

    Positive result

    Ammonia

    Carbon dioxide

    Hydrogen

    Oxygen

Cards in this collection (41)

  • Complete the table of tests for gases.

    Gas

    Test

    Positive result

    Ammonia

    Carbon dioxide

    Hydrogen

    Oxygen

    Gas

    Test

    Positive result

    Ammonia

    Hold damp red litmus paper near the gas

    Paper turns blue

    Carbon dioxide

    Bubble gas through limewater

    Limewater turns cloudy white

    Hydrogen

    Hold a burning splint at the mouth of the tube

    Burns with a squeaky pop

    Oxygen

    Insert a glowing splint into the tube

    Splint relights

  • How do you test for carbon dioxide gas?

    To test for carbon dioxide, bubble the gas through limewater (calcium hydroxide solution). If carbon dioxide is present, the limewater turns cloudy white due to the formation of insoluble calcium carbonate.

  • True or False?

    A burning splint gives a squeaky pop in the presence of oxygen.

    False.

    The squeaky pop test is for hydrogen, not oxygen. To test for oxygen, you use a glowing splint — if oxygen is present, the splint relights.

  • What is limewater?

    Limewater is an aqueous solution of calcium hydroxide. It is used to test for carbon dioxide gas — it turns cloudy white when CO2 is present.

  • What happens when chlorine gas contacts damp blue litmus paper, and why does it bleach it?

    Damp blue litmus paper first turns red and then bleaches white in the presence of chlorine gas. It turns red because acids are produced when chlorine dissolves in water, and then the chlorine bleaches it white.

  • To test for hydrogen gas, hold a .......... at the mouth of the test tube. If hydrogen is present, you will hear a loud "squeaky pop".

    To test for hydrogen gas, hold a burning splint at the mouth of the test tube. If hydrogen is present, you will hear a loud "squeaky pop".

  • True or False?

    Ammonia gas turns damp red litmus paper blue.

    True.

    Ammonia is an alkaline gas. It turns damp red litmus paper blue, which is the standard chemical test for this gas.

  • Why must the litmus paper be damp when testing for ammonia or chlorine?

    The litmus paper must be damp because the gases must dissolve in water to react with the indicator. Without moisture, the gas cannot interact with the litmus paper to cause a colour change.

  • What is a glowing splint?

    A glowing splint is a piece of wood that has been lit and then blown out so it continues to glow without a flame. It is used to test for oxygen gas — the splint relights if oxygen is present.

  • Complete the table of flame test colours.

    Metal cation

    Flame colour

    Li+

    Na+

    K+

    Ca2+

    Cu2+

    Metal cation

    Flame colour

    Li+

    Red

    Na+

    Yellow

    K+

    Lilac

    Ca2+

    Orange-red

    Cu2+

    Blue-green

  • Why must the nichrome wire be cleaned in acid before carrying out a flame test?

    The wire is cleaned in acid to remove any contamination from previous tests. If impurities remain, more than one metal ion may be present on the wire, causing the flame colours to mix and preventing accurate identification of the ion.

  • True or False?

    Potassium ions produce a red flame in a flame test.

    False.

    Potassium ions (K+) produce a lilac flame. It is lithium ions (Li+) that produce a red flame.

  • What is a flame test?

    A flame test is a technique used to identify the positive metal ion (cation) in a compound by observing the colour of the flame produced when a sample is heated in a Bunsen burner flame.

  • What is the flame colour produced by copper(II) ions in a flame test?

    Copper(II) ions (Cu2+) produce a blue-green flame in a flame test. This is the only metal ion in the syllabus that gives a blue-green colour.

  • In a flame test, the nichrome wire is first dipped into .......... and heated in the blue flame until no .......... is seen, to remove contamination.

    In a flame test, the nichrome wire is first dipped into dilute acid and heated in the blue flame until no colour change is seen, to remove contamination.

  • True or False?

    Sodium ions produce a yellow flame in a flame test.

    True.

    Sodium ions (Na+) produce a yellow flame. The colour is distinctive and easy to observe.

  • How do you carry out a flame test?

    To carry out a flame test, clean a nichrome or platinum wire by dipping it in dilute acid and heating it until there is no colour change. Then dip the wire into the sample and hold it in the edge of the blue flame. Observe the colour produced to identify the metal ion.

  • Define nichrome.

    Nichrome is an unreactive metal alloy used in flame tests. Because it is unreactive, it does not produce its own flame colour, allowing the colour from the metal ion in the sample to be seen clearly.

  • Complete the table showing the results of adding NaOH to metal ion solutions.

    Metal ion

    Effect of adding NaOH

    Cu2+

    Fe2+

    Fe3+

    NH4+

    Metal ion

    Effect of adding NaOH

    Cu2+

    Light blue precipitate formed

    Fe2+

    Green precipitate formed

    Fe3+

    Brown precipitate formed

    NH4+

    Ammonia gas produced — turns damp red litmus paper blue

  • Why can sodium hydroxide solution be used to identify metal cations in solution?

    When sodium hydroxide is added to a metal cation solution, the metal ions form insoluble hydroxide precipitates. The colour of the precipitate is characteristic of the specific metal ion present, allowing identification.

  • True or False?

    Fe2+ ions form a brown precipitate when sodium hydroxide is added.

    False.

    Fe2+ ions form a green precipitate with sodium hydroxide. It is iron(III) ions (Fe3+) that form the brown precipitate.

  • What is a cation?

    A cation is a positively charged ion. Metal cations in solution can be identified by the colour of the precipitate they form when sodium hydroxide solution is added.

  • How do you test for ammonium ions using sodium hydroxide?

    To test for ammonium ions (NH4+), add sodium hydroxide solution to the sample and heat gently. If ammonium ions are present, ammonia gas is produced. Hold damp red litmus paper near the gas — it turns blue to confirm.

  • True or False?

    Cu2+ ions form a light blue precipitate when sodium hydroxide is added.

    True.

    Cu2+ ions react with sodium hydroxide to form a light blue, insoluble copper(II) hydroxide precipitate.

  • When sodium hydroxide is added to a solution containing Fe3+ ions, a .......... coloured precipitate is formed.

    When sodium hydroxide is added to a solution containing Fe3+ ions, a brown coloured precipitate is formed.

  • Complete the table of anion tests.

    Anion

    Test reagent(s)

    Positive result

    Carbonate (CO32–)

    Halide ions (Cl-, Br-, I-)

    Sulfate (SO42-)

    Anion

    Test reagent(s)

    Positive result

    Carbonate (CO32–)

    Dilute acid, then limewater

    Limewater turns cloudy white

    Halide ions (Cl-, Br-, I-)

    Dilute nitric acid, then silver nitrate solution

    Coloured precipitate forms

    Sulfate (SO42-)

    Dilute HCl, then barium chloride solution

    White precipitate forms

  • How do you test for carbonate ions?

    Add dilute acid to the sample. If carbonate ions are present, fizzing occurs as CO2 gas is released. Bubble this gas through limewater — it turns cloudy white if carbonate is present.

  • True or False?

    Bromide ions form a white precipitate when silver nitrate solution is added.

    False.

    Bromide ions (Br-) form a cream precipitate of silver bromide. It is the chloride ion that forms a white precipitate with silver nitrate.

  • What is an anion?

    An anion is a negatively charged ion. In chemical tests, anions are identified using reagents that produce characteristic precipitates or gas reactions specific to each ion.

  • Why must nitric acid (not hydrochloric acid) be used when testing for halide ions?

    Nitric acid is used instead of hydrochloric acid because hydrochloric acid contains chloride ions (Cl-), which would react with silver nitrate to produce a false white precipitate. Using nitric acid avoids this interference, giving an accurate result.

  • To test for sulfate ions, acidify the sample with dilute ..........and then add .......... solution. A white precipitate of barium sulfate confirms the presence of sulfate ions.

    To test for sulfate ions, acidify the sample with dilute hydrochloric acid and then add barium chloride solution. A white precipitate of barium sulfate confirms the presence of sulfate ions.

  • True or False?

    Iodide ions form a yellow precipitate when silver nitrate solution is added.

    True.

    Iodide ions (I-) react with silver nitrate to form a yellow precipitate of silver iodide.

  • How do you test for sulfate ions?

    To test for sulfate ions, acidify the sample with dilute hydrochloric acid, then add a few drops of barium chloride solution. A white precipitate of barium sulfate forms if sulfate ions are present.

  • What is a precipitate?

    A precipitate is an insoluble solid that forms when two solutions are mixed. In anion tests, precipitates form when the test reagent reacts with the target ion to produce an insoluble compound.

  • What precipitate colours are formed when chloride, bromide and iodide ions react with silver nitrate solution?

    The silver halide precipitate colours are:

    1. Chloride ions (Cl-) form a white precipitate of silver chloride

    2. Bromide ions (Br-) form a cream precipitate of silver bromide

    3. Iodide ions (I-) form a yellow precipitate of silver iodide

  • What are the two types of test that can be used to identify water?

    Water can be identified by a chemical test and a physical test. The chemical test uses anhydrous copper(II) sulfate, while the physical test checks the boiling point of the liquid.

  • Define anhydrous.

    Anhydrous describes a substance that contains no water molecules. Anhydrous copper(II) sulfate is white but turns blue when water is added, making it useful as a chemical test for water.

  • True or False?

    Anhydrous copper(II) sulfate turns from white to blue when water is added.

    True.

    Anhydrous copper(II) sulfate (CuSO4) is white. When water is added, it reacts to form hydrated copper(II) sulfate (CuSO4.5H2O (s)), which is blue.

  • In the chemical test for water, anhydrous copper(II) sulfate changes colour from .......... to .......... when water is present.

    In the chemical test for water, anhydrous copper(II) sulfate changes colour from white to blue when water is present.

  • Why is checking the boiling point a physical test for the purity of water?

    Pure water boils at exactly 100 °C. By heating a sample and measuring its boiling point, you can check whether it is pure — impurities raise the boiling point above 100 °C, indicating the water is not pure.

  • True or False?

    Impurities in water raise its boiling point above 100 °C.

    True.

    Pure water boils at exactly 100 °C. The presence of impurities raises the boiling point, so a sample boiling above 100 °C is not pure water.

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