Temperature (Edexcel IGCSE Science (Double Award) (Modular): Physics Unit 2): Revision Note

Exam code: 4XSD1

Temperature & speed

  • Imagine molecules of gas that are free to move around in a box

  • The molecules in the gas move around randomly at high speeds, colliding with surfaces and exerting pressure upon them

  • The temperature of a gas is a measure of the average speed of the molecules:

    • The higher the temperature of the gas, the faster the molecules move

    • This is because they have a greater average speed

Gas molecules move about randomly at high speeds

Temperature & kinetic energy

  • The temperature of a substance is related to the average kinetic energy of its molecules

  • The higher the temperature, the higher the average kinetic energy of the molecules, and vice versa

    • This means they move faster at higher temperatures

    • This applies to all states of matter, although the motion of particles in a solid is different from that of particles in a gas

  • For a gas, the internal energy can be taken as the sum of the kinetic energies of all the molecules

    • In a gas, the intermolecular forces are negligible, so the contribution from potential energy can be taken as zero

    • This is different from a solid or liquid, where the internal energy includes contributions from both kinetic and potential energy

Change in internal energy, downloadable AS & A Level Physics revision notes

As the container is heated up, the gas molecules move faster with higher kinetic energy. The energy stored within the system - the internal energy - therefore increases

  • If the temperature of a gas is increased, the particles move faster and gain kinetic energy

    • They collide more often with each other and the container walls, leading to an increase in pressure

  • The temperature (in Kelvin) is proportional to the average kinetic energy of the molecules:

T ∝ KE

Worked Example

When a liquid evaporates, molecules escape from the surface of the liquid.

What happens to the temperature of the liquid and the average kinetic energy of the molecules within it?

 

Temperature / K

Average kinetic energy of the molecules

A

Increases

Increases

B

Decreases

Decreases

C

Stays the same

Stays the same

D

Decreases

Increases

Answer: B

  • When evaporation takes place, the more energetic molecules leave the surface of the liquid

  • Since the more energetic molecules have left, the average kinetic energy per molecule must decrease

    • Therefore, A & D are not correct

  • Temperature is proportional to the average kinetic energy per molecule, therefore, the temperature also decreases

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