Electrons & Ions (Edexcel International AS Chemistry): Multiple Choice Questions

Exam code: XCH11

32 mins19 questions
1
1 mark

Which equation represents the second ionisation energy of chlorine?

  • Cl− (g) + e−→ Cl2− (g)

  • Cl (g) + 2e− → Cl2− (g)

  • 2Cl (g) → 2Cl+ (g) + 2e−

  • Cl+ (g) → Cl2+ (g) + e−

2
1 mark

Which equation represents the second ionisation energy of magnesium?

  • Mg (g) → Mg2+ (g) + 2e−

  • Mg+ (g) → Mg2+ (g) + e−

  • Mg (s) → Mg2+ (s) + 2e−

  • Mg+ (s) → Mg2+ (s) + e−

3
1 mark

Several factors may affect ionisation energies:

I) the number of protons increases

II) the outer electron is further from the nucleus

III) the amount of shielding increases

IV) the number of unpaired outer electrons increases

Which factors explain the decrease in ionisation energy as Group 1 is descended?

  • I and II

  • II and III

  • III and IV

  • I, II, III and IV

4
1 mark

Why is the second ionisation energy of magnesium greater than its first ionisation energy?

  • The Mg+ ion is larger than the Mg atom

  • The second electron is removed from a positive ion

  • The second electron is removed from an inner shell

  • The nuclear charge of Mg+ is greater than that of Mg

5
1 mark

In which block of the Periodic Table is zirconium, Zr, found?

  • d block

  • f block

  • p block

  • s block

1
1 mark

The graph shows log (ionisation energy) against ionisation number for the successive ionisations of an element.

q5-paper-1-june-2021-edexcel-ial-chemistry

In this element, how many quantum shells contain electrons, and how many electrons are in the outer quantum shell?

 

 

Number of quantum shells containing electrons

Number of electrons in the outer quantum shell

☐

A

3

2

☐

B

3

5

☐

C

5

2

☐

D

5

5

    2
    1 mark

    A stable ion, M3+, contains 18 electrons.

    In which block of the Periodic Table is element M found?

    • s

    • p

    • d

    • f

    3
    1 mark

    Which ion has the electronic configuration 1s22s22p63s23p6 in its ground state?

    • Al3+

    • Cl−

    • N3−

    • Na+

    4
    1 mark

    A p-block element in Period 3 of the Periodic Table reacts to form an ionic compound.

    What could be the electronic configuration of the ion formed by this element?

    • 1s22s22p63s2

    • 1s22s22p63s23p6

    • 1s22s22p63s23p63d10

    • 1s22s22p63s23p63d104s24p6

    5
    1 mark

    Which Period 3 element has the highest second ionisation energy?

    • sodium

    • magnesium

    • chlorine

    • argon

    6
    1 mark

    Which of these elements has atoms with only one unpaired electron?

    • boron

    • carbon

    • nitrogen

    • oxygen

    7
    1 mark

    Element X is in Period 2. Its first seven ionisation energies are shown.

    Ionisation

    1st

    2nd

    3rd

    4th

    5th

    6th

    7th

    Ionisation energy / kJ mol−1

    1314

    3388

    5301

    7469

    10 989

    13 327

    71 330

    What is the electronic configuration of X?

    • 1s2 2s2 2p2

    • 1s2 2s2 2p3

    • 1s2 2s2 2p4

    • 1s2 2s2 2p5

    8
    1 mark

    The first five ionisation energies of four elements in Period 3 are shown.

    Ionisation energy / kJ mol−1

    Element

    1st

    2nd

    3rd

    4th

    5th

    A

    1251

    2298

    3822

    5159

    6542

    B

    738

    1451

    7733

    10 543

    13 630

    C

    496

    4562

    6910

    9543

    13 354

    D

    787

    1577

    3232

    4356

    16 091

    Which element could be magnesium?

      1
      1 mark

      Element Q reacts with sulfur to form an ionic compound.

      The first five ionisation energies of Q are shown.

      Ionisation

      1st

      2nd

      3rd

      4th

      5th

      Ionisation energy / kJ mol−1

      550

      1064

      4138

      5500

      6910

      What is the formula of the compound formed between Q and sulfur?

      • QS

      • Q2S

      • QS2

      • Q2S3

      2
      1 mark

      The first eight ionisation energies of two elements, X and Y, are shown.

      Ionisation energy / kJ mol−1

      Element

      1st

      2nd

      3rd

      4th

      5th

      6th

      7th

      8th

      X

      590

      1145

      4912

      6491

      8153

      10 496

      12 270

      14 206

      Y

      1012

      1907

      2914

      4964

      6274

      21 267

      25 431

      29 872

      X and Y both form ions with the same electronic configuration as argon.

      What are X and Y?

      • calcium and phosphorus

      • calcium and sulfur

      • potassium and chlorine

      • potassium and phosphorus

      3
      1 mark

      Element E is in Period 2. Its first six ionisation energies are shown.

      Ionisation

      1st

      2nd

      3rd

      4th

      5th

      6th

      Ionisation energy / kJ mol−1

      1402

      2856

      4578

      7475

      9445

      53 267

      The increase from the third to the fourth ionisation energy is larger than the increase from the second to the third.

      Which statement explains this?

      • The fourth electron is removed from the 1s sub-shell

      • The fourth electron is removed from the 2s sub-shell

      • The fourth electron is removed from the 2p sub-shell

      • The fourth electron is removed from a shell closer to the nucleus

      4
      1 mark

      Which of these gaseous ions has exactly three unpaired electrons in its ground state?

      • Cr3+

      • Cu2+

      • Fe2+

      • Mn2+

      5
      1 mark

      How many orbitals contain at least one electron in a ground-state iron atom?

      • 7

      • 13

      • 14

      • 15