OxidatIon & Reduction in Terms of Electrons (OCR GCSE Chemistry A (Gateway)): Revision Note

Exam code: J248

Oxidation & Reduction in Terms of Electrons

Higher Tier Only

  • For reactions not involving oxygen, we can look at oxidation and reduction in terms of losing and gaining electrons

  • Oxidation is the loss of electrons

  • Reduction is the gain  of electrons 

  • We can use half and ionic equations to determine which species has been oxidised and reduced in terms of electrons 

  • A displacement reaction occurs between magnesium and copper sulfate: 

Mg (s) +  CuSO4 (aq) →   MgSO4 (aq) + Cu (s) 

  • The  ionic equation for this reactions is:

Mg (s) + Cu2+ (aq)  → Mg2+ (aq)  + Cu (s)

  • This can be split into two half equations which demonstrate oxidation and reduction individually:

Mg → Mg2+ + 2e–

Cu2+ + 2e–→ Cu

  • The magnesium atoms are oxidised as they lose electrons

  • The copper ions are reduced as they gain electrons

Worked Example

Zinc displaces copper from a solution of copper(II)sulfate.

Using ionic equations, determine which species undergoes oxidation and which species undergoes reduction

Answer:

  • Write the overall balanced symbol equation:

Zn (s) + CuSO4 (aq)→ ZnSO4 (aq) + Cu (s)

  • Write out the ions separately:

Zn (s) + Cu2+(aq) + SO42- (aq) →Zn2+(aq) + SO42-(aq) + Cu (s)

  • Eliminate ions that occur on both sides (spectator ions):

Zn (s) + Cu2+(aq) →  Zn2+(aq) + Cu (s)

  • Identify which species has lost or gained electrons

    • Zinc has lost electrons and been oxidised:

Zn →  Zn2+  +  2e-

  • Copper ions have gained electrons and been reduced:

Cu2+ +  2e-  →  Cu

Examiner Tips and Tricks

A handy way of remembering definitions for oxidation and reduction for electrons is:

OIL RIG: Oxidation Is Loss of electrons, Reduction Is Gain

Unlock more, it's free!

Join the 100,000+ Students that ❤️ Save My Exams

the (exam) results speak for themselves:

Build on this topic

Alexandra Brennan

Author: Alexandra Brennan

Expertise: Chemistry Content Creator / Senior Marketing Executive

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.

Caroline Carroll

Reviewer: Caroline Carroll

Expertise: Head of Content Delivery

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about delivering high-quality resources to help students achieve their full potential.