Reactions Of Acids (AQA GCSE Combined Science: Synergy: Physical Sciences): Revision Note

Exam code: 8465

Reactions of acids with metals

  • Only metals above hydrogen in the reactivity series will react with dilute acids

    • Therefore copper can not react with acids

  • The more reactive the metal then the more vigorous the reaction will be

  • Metals that are placed high on the reactivity series such as potassium and sodium are very dangerous and react explosively with acids

  • When acids react with metals they form a salt and hydrogen gas:

  • The general equation is:

metal + acid ⟶ salt + hydrogen

  • Some examples of metal-acid reactions and their equations are given below:

Metal

Sulfuric acid

Hydrochloric acid

 Magnesium 

 Mg (s) + H2SO4 (aq) → MgSO4 (aq) + H2 (g)

 Mg (s) + 2HCl (aq) → MgCl2 (aq) + H2 (g)

 Zinc

Zn (s) + H2SO4 (aq) → ZnSO4 (aq) + H2 (g) 

 Zn (s) + 2HCl (aq) → ZnCl2 (aq) + H2 (g)

 Iron

Fe (s) + H2SO4 (aq) → FeSO4 (aq) + H2 (g)

 Fe (s) + 2HCl (aq) → FeCl2 (aq) + H2 (g)

Test for Hydrogen Gas

  • The test for hydrogen consists of holding a burning splint at the open end of a test tube of gas

  • If the gas is hydrogen it burns with a loud “squeaky pop

The diagram shows a lit splint being placed at the neck of a test-tube of gas, and giving a squeaky pop sound for the presence of hydrogen
A burning splint gives a 'squeaky pop' sound

Examiner Tips and Tricks

Sulfuric acid reacts with metals and produces sulfate salts while hydrochloric acid produces chloride salts.

Carbonate & Acid Reactions

  • When an acid reacts with a base, a neutralisation reaction occurs

  • A base is a chemical that neutralises acids

  • Examples of bases include:

    • Metal oxides, e.g. copper(II) oxide, CuO

    • Metal hydroxides, e.g. sodium hydroxide, NaOH

    • Metal carbonates, e.g. calcium carbonate, CaCO3 

  • Bases have pH values above 7

  • Many bases are insoluble in water

  • Some bases dissolve in water and are called alkalis because they form an alkaline solution

Reactions of acids with metal carbonates

  • Metal carbonates act as bases

    • They react with acids in a neutralisation reaction to form the corresponding metal saltcarbon dioxide and water

  • The following are some specific examples of reactions between acids and metal carbonates:

2HCl + Na2CO3 ⟶ 2NaCl + H2O + CO2

H2SO4 + CaCO3⟶ CaSO4 + H2O + CO2

2HNO3 + MgCO3 → Mg(NO3)2 + H2O + CO2

  • These reactions are easy to distinguish by the effervescence (fizzing) caused by the release of carbon dioxide gas

Testing for carbon dioxide gas

  • The test for carbon dioxide involves bubbling the gas through an aqueous solution of limewater (calcium hydroxide)

  • If the gas is carbon dioxide, the limewater turns cloudy white

The diagram shows carbon dioxide bubbling through limewater, which turns cloudy / milky to confirm the presence of carbon dioxide
Limewater turns cloudy white in the presence of carbon dioxide

Examiner Tips and Tricks

  • For a neutralisation reaction to occur, water must be formed.

    • Therefore, the reaction between an acid and a metal carbonate is a neutralisation reaction.

  • If an acid-base reaction effervesces (fizzes), then the base must be a metal carbonate as carbon dioxide gas is produced.

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