Ionisation Energy (Cambridge (CIE) A Level Chemistry): Exam Questions

Exam code: 9701

2 hours24 questions
1
1 mark

Which statement defines the first ionisation energy of an element?

  • The energy required to remove one electron from one atom in the gaseous state.

  • The energy required to remove one mole of electrons from one mole of atoms in the solid state.

  • The energy required to remove one mole of electrons from one mole of gaseous atoms to form one mole of gaseous 1+ ions.

  • The energy required to remove one mole of electrons from one mole of gaseous 1+ ions.

2
1 mark

Which is the correct equation for the first ionisation energy for magnesium?

  • Mg → Mg+ + e-

  • Mg+ (g) → Mg2+ (g) + e-

  • Mg (g) → Mg+ (g) + e-

  • Mg+ → Mg2+ + e-

3
1 mark

Which statement explains why the second ionisation energy of magnesium is greater than the first ionisation energy?

  • There is less shielding after the first electron is removed.

  • The ionic radius of the magnesium ion increases after the first ionisation.

  • The nuclear charge increases after the first ionisation.

  • There is greater attraction between the nucleus and the remaining outer electrons.

4
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1 mark

The first five ionisation energies of an element are shown below.

Line graph of ionisation energy versus ionisation number, showing a gradual rise from 1–3 then a very large jump at 4 and a further rise at 5

What element could this ionisation energy graph belong to?

  • Al

  • N

  • Na

  • P

5
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1 mark

Which statement does not explain the increase in first ionisation energy across a period?

  • Nuclear charge increases.

  • Atomic radius decreases.

  • Shielding remains constant.

  • The number of electrons increases.

1
1 mark

The second ionisation energy of magnesium is 1451 kJ mol-1

Which equation correctly represents this statement?

  • Mg (g) → Mg+ (g) + e- ΔH = +1451 kJ mol-1

  • Mg+ (g) → Mg2+ (g) + e- ΔH = +1451 kJ mol-1

  • Mg (g) → Mg2+ (g) + 2e- ΔH = +1451 kJ mol-1

  • Mg (g) → Mg+ (g) + e- ΔH = -1451 kJ mol-1

2
1 mark

The successive ionisation energies of element X are shown in the table below. In which group of the Periodic Table is element X found?

Ionisation number of X

1

2

3

4

5

6

7

8

Ionisation energy (kJ mol-1)

1314

3388

5301

7469

10989

13327

71337

84080

  • 13

  • 14

  • 15

  • 16

3
1 mark

X, Y and Z are consecutive elements in Period 3 of the Periodic Table. Element Y has the highest first ionisation energy and also the lowest melting point of these three elements.

Which row could identify X, Y and Z?

  • silicon, phosphorus, sulfur 

  • sodium, magnesium, aluminium

  • aluminium, silicon, phosphorus

  • magnesium, aluminium, silicon

4
1 mark

Successive ionisation energies for an element, Y, are shown in the table below.

Electrons removed

1st

2nd

3rd

4th

5th

Ionisation energy / kJ mol-1

736

1450

7740

10500

13600

What is the most stable ion formed by Y?

  • Y+

  • Y2+

  • Y3+

  • Y4+

5
1 mark

Values for the successive ionisation energies of an unknown element are given in the table below.

First ionisation energy / kJ mol-1

Second ionisation energy / kJ mol-1

Third ionisation energy / kJ mol-1

Fourth ionisation energy / kJ mol-1

420

3600

4400

5900

In which group of the Periodic Table is this element found?

  • 1

  • 2

  • 13

  • 14

6
1 mark

The graph below shows the variation of a physical property for elements in Period 3 (Na to Ar).

Line graph showing values of a physical property against atomic numbers for elements Na to Ar, peaking at Si and dropping towards Ar.

Which physical property is shown?

  • atomic radius

  • electrical conductivity

  • melting point

  • first ionisation energy

1
1 mark

Element X is in period 2 and has the first seven ionisation energies in kJ mol-1 as shown.

1300

3380

5330

7460

11 010

13 320

71 200

What is the electronic configuration of element X?

  • 1s2 2s2 2p2

  • 1s2 2s2 2p3

  • 1s2 2s2 2p4

  • 1s2 2s2 2p6

2
1 mark

Between which two successive ionisation energies of oxygen is the largest increase?

  • First and second

  • Fifth and sixth

  • Sixth and seventh

  • Seventh and eighth

3
1 mark

The first ionisation energy of beryllium is greater than that of boron.

Which statement explains why?

  • Boron has a full outer shell.

  • Boron has a larger atomic radius than beryllium.

  • The outer electron in boron is in a 2p subshell, which is at a higher energy and further from the nucleus than the 2s subshell of beryllium.

  • The proton number of beryllium is greater than that of boron.

4
1 mark

The electronic configurations of four different atoms are shown. 

Which atom has the highest first ionisation energy?

  • 1s2 2s2 2p6 3s2

  • 1s2 2s2 2p4

  • 1s2 2s2 2p6 

  • 1s2 2s2 

5
1 mark

The table gives the successive ionisation energies for an element R.

1st

2nd

3rd

4th

5th

6th

Ionisation energy / kJ mol-1

950

1800

2700

4800

6000

12300

What could be the oxidation state of element R in its chloride?

  • +1

  • +2

  • +3

  • +4