Organic Chemistry: Carboxylic Acids (Edexcel International A Level (IAL) Chemistry): Exam Questions

Exam code: YCH11

35 mins13 questions
1
1 mark

Butanoic acid may be prepared by the acid hydrolysis of

  • butyl ethanoate

  • 1-chlorobutane

  • ethyl butanoate

  • propanenitrile

2
1 mark

Compound X, C4H10O, is oxidised to form compound Y.

Compound Y reacts with ethanol in the presence of concentrated sulfuric acid to give an ester, Z.

Which of these could be the formula of Z?

  • CH3COOC(CH3)3

  • CH3CH2COO(CH2)3CH3

  • (CH3)2CHCOOCH2CH3

  • CH3CH2COOCH2CH(CH3)2

3
1 mark

Terylene is a polyester derived from ethane-1,2-diol and terephthalic acid.

q14-paper-4-oct-2021-edexcel-ial-chemistry

What is the structure of the repeat unit of terylene?

q14-2-paper-4-oct-2021-edexcel-ial-chemistry
    4
    1 mark

    Propyl ethanoate, CH3COOCH2CH2CH3, is hydrolysed with aqueous sodium hydroxide.

    Which products are formed?

    • CH3COOH and CH3CH2CH2OH

    • CH3COOH and CH3CH2CH2ONa

    • CH3COONa and CH3CH2CH2OH

    • CH3COONa and CH3CH2CH2ONa

    5
    1 mark

    Which of these compounds is a product of the hydrolysis of CH3COOC3H7 by refluxing with aqueous sodium hydroxide?

    • CH3OH

    • C3H7OH

    • C3H7COOH

    •  C3H7COONa+

    6
    1 mark

    The formation of esters and the hydrolysis of esters are reactions that are slow under normal laboratory conditions.

    What speeds up these reactions?

     

     

    Esterification

    Hydrolysis

    A

    acids only

    acids only

    B

    acids only

    acids and bases

    C

    bases only

    bases only

    D

    bases only

    acids and bases

      7
      Sme Calculator
      1 mark

      2.95 g of ethanoic acid is produced from 2.50 g of ethanol.

      What is the percentage yield of ethanoic acid?

      [Molar masses in g mol−1: ethanoic acid = 60 ethanol = 46]

      • 65.0 %

      • 84.7 %

      • 90.5 %

      • 118 %

      8
      1 mark

      Ethanoyl chloride (CH3COCl) reacts with ethanol at room temperature.

      What is the organic product of this reaction?

      • ethanoic acid

      • ethanol

      • ethoxyethane

      • ethyl ethanoate

      9
      1 mark

      The concentration of reactant A was monitored against time during a reaction. The results are shown below.

      Graph showing a linear decrease in concentration [A] in mol dm⁻³ over time t in seconds, from 1.0 at 0s to 0.0 at 100s.

      What is the order of the reaction with respect to A?

      • First order

      • Second order

      • Third order

      • Zero order

      10
      1 mark

      The Arrhenius plot of ln k against 1/T for a reaction is shown.

      Graph showing ln k versus 1/T; an inverse linear relationship is depicted, with ln k decreasing as 1/T increases from 2.0 to 3.0.

      The gradient of the line is −6005 K.

      [Gas constant R = 8.31 J K⁻¹ mol⁻¹]

      Calculate the activation energy of this reaction.

      • −49.9 kJ mol⁻¹

      • 49.9 kJ mol⁻¹

      • 722 kJ mol⁻¹

      • 4.99 × 10⁴ kJ mol⁻¹

      1a
      1 mark

      The substance known as PHBV is a biodegradable polymer formed from 3-hydroxybutanoic acid and 3-hydroxypentanoic acid.

      q9-paper-4-2021-june-edexcel-ial-chemistry

      Which of these is the repeat unit of the polymer?


      q9a-paper-4-2021-june-edexcel-ial-chemistry
        1b
        1 mark

        What reaction occurs when PHBV biodegrades to its monomers?

        • condensation

        • hydrolysis

        • hydration

        • hydrogenation