Periodicity of Physical Properties of the Elements in Period 3 (Cambridge (CIE) AS Chemistry): Exam Questions

Exam code: 9701

51 mins14 questions
1a
1 mark

State the trend in atomic radius across Period 3.

1b
4 marks

The electrical conductivity of the elements in Period 3 varies across the period as shown in Fig. 1.1.

Bar graph showing electrical conductivity of Period 3 elements from Na to Cl

Fig. 1.1

i) Explain why aluminium has a much higher electrical conductivity than sulfur. You should refer to the structure of both elements.

[2]

ii) Explain why aluminium has a higher electrical conductivity than magnesium.

[2]

1c
5 marks

The melting points of three successive elements in Period 3 are shown in Table 1.1.

Table 1.1

Element

Melting point / °C

Aluminium

660

Silicon

1410

Phosphorus

44

i) Explain, referring to its structure and bonding, why the melting point of silicon is high.

[3]

ii) Explain, referring to its structure and bonding, why the melting point of phosphorus is low.

[2]

1a
3 marks

The elements in Period 3 of the Periodic Table show variations in their behaviour across the period.

Fig. 3.1 shows the variation of melting points of the elements across Period 3.

Graph showing melting points of Period 3 elements from Na to Cl, with a peak at Si

Fig. 3.1

Explain the general increase in melting point from Na to Al.

1b
3 marks

Explain the variation of melting points from P to Ar.

1c
2 marks

Explain why Si has a much higher melting point than any of the other elements in the period.

1d
5 marks

Going across Period 3, a trend in electronegativity can also be observed.

i) Define electronegativity.

[2]

ii) Complete Fig. 3.2 to show how electronegativity changes along Period 3.

Blank graph with Period 3 elements on the x-axis and electronegativity on the y-axis

Fig. 3.2

[1]

iii) Explain your answer to part (ii).

[2]

2a
4 marks

The properties of elements and their compounds show similarities, differences and trends depending on the positions of the elements in the Periodic Table.

i) State what is meant by the term ionic radius.

[1]

ii) Explain why a cation is smaller than its parent atom, whereas an anion is larger than its parent atom.

[3]

2b
2 marks

On Fig. 2.1, sketch a graph to show the trend in the ionic radius of successive elements in Period 3.

Blank graph with Period 3 elements on the x-axis and ionic radius on the y-axis

Fig. 2.1

2c
3 marks

Explain the trend shown in part (b).

3a
3 marks

Table 3.1 shows the melting points and atomic radii of the elements in Period 3, Na to Cl.

Table 3.1

Element

Na

Mg

Al

Si

P

S

Cl

Melting point / °C

98

649

660

1410

44

113

–101

Atomic radius / pm

186

160

143

118

110

102

99

Explain why magnesium has a higher melting point than sodium.

3b
3 marks

Explain why phosphorous has a lower melting point than sulfur.

3c
3 marks

Explain the trend in atomic radius shown in Table 3.1.