Dot-&-Cross Diagrams (Cambridge (CIE) AS Chemistry): Exam Questions

Exam code: 9701

36 mins13 questions
1a
3 marks

Draw dot-and-cross diagrams for the following molecules.

Show outer shell electrons only.

i) Hydrogen cyanide, HCN.

Blank dot-and-cross diagram template for hydrogen cyanide showing the atom positions of H, C, and N with blank space for electrons

[1]

ii) Carbon dioxide, CO2.

Blank dot-and-cross diagram template for carbon dioxide showing the atom positions of O, C, and O with blank space for electrons

[1]

iii) Boron trifluoride, BF3.

Blank dot-and-cross diagram template for boron trifluoride showing the atom positions of B and three F atoms with blank space for electrons

[1]

1b
2 marks

Use your diagrams in (a) to deduce which of the three molecules is most likely to form a coordinate (dative covalent) bond. Explain your answer.

1c
2 marks

i) Draw a dot-and-cross diagram for the product of boron trifluoride and ammonia.

Show outer shell electrons only.

[1]

ii) Explain how the coordinate (dative covalent) bond forms between the boron trifluoride and ammonia molecules.

[1]

2a
2 marks

Phosphorus tribromide and sulfur tetrafluoride are two colourless compounds which both react with water to form toxic products. 

Draw diagrams to show the arrangement of outer electrons in both compounds.

2b
2 marks

State the shape of, and the Br-P-Br bond angle in, a molecule of PBr3.

2c
2 marks

Explain why molecules of PBr3 and SF4 are polar.

3a
1 mark

Construct an equation for the reaction of ammonia, NH3, with a hydrogen ion.

3b
2 marks

Predict the shapes of an ammonia molecule and an ammonium ion.

3c
2 marks

Draw a dot-and-cross diagram to show the bonding in the ammonium ion.

Show outer shell electrons only.

1a
2 marks

Draw a dot-and-cross diagram for the nitrate(V) ion, NO3-.

Show outer shell electrons only.

1b
2 marks

An ionic compound has the empirical formula H4N2O3

Suggest the formulae of the ions present in this compound.

1c
2 marks

Draw a dot-and-cross diagram for the CN- ion.

Show outer shell electrons only.

1d
3 marks

Compare the C≡N bond energy and bond length in the cyanide ion, CN-, with the C-N bond energy and bond length in methylamine, CH3NH2.

Explain your answer.