Temperature & Pressure (OCR GCSE Physics A (Gateway)): Revision Note

Exam code: J249

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Written by: Ashika

Reviewed by: Caroline Carroll

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Molecules in a Gas

Motion of Particles in a Gas

  • Molecules in a gas are in constant random motion at high speeds

  • Random motion means that the molecules are travelling in no specific path and undergo sudden changes in their motion if they collide:

    • With the walls of its container

    • With other molecules

  • The random motion of tiny particles in a fluid is known as Brownian motion

Eight gas molecules moving randomly inside a container. Green arrows point in different directions, with curved motion lines showing movement and collisions with the container walls.
Random motion of gas molecules in a container

Pressure

  • Molecules of gas in a container will collide with the container walls

  • Pressure is defined as the force exerted per unit area 

Pressure equation, downloadable AS & A Level Physics revision notes
  • Pressure is measured in pascals (Pa)

  • The area should always be the cross-sectional area of the object

    • This means the area where the force is at right angles to it

  • This equation can be rearranged with the help of a formula triangle:

Formula triangle for pressure: force (F) at the top, with pressure (P) and area (A) in the two lower sections, showing F equals P times A.
Pressure, force, area formula triangle
  • Imagine molecules of gas that are free to move around in a box

  • The molecules in the gas move around randomly at high speeds, colliding with surfaces and exerting pressure upon them

  • The temperature of a gas is related to the average speed of the molecules:

    • The hotter the gas, the faster the molecules move and vice versa

    • Hence, the molecules collide with the surface of the walls more frequently and with more force

    • This increases the pressure

A box containing seven blue gas molecules, each with arrows pointing in different directions to show their fast, random motion and collisions with the container walls.
Gas molecules hit the sides of the container which creates pressure. A higher temperature increases the average speed of the molecules, increasing the pressure

Temperature & Pressure

  • The motion of molecules in a gas changes according to the temperature

  • As the temperature of a gas increases, the average speed of the molecules also increases

  • Since the average kinetic energy depends on their speed, the kinetic energy of the molecules also increases if its volume remains constant

    • The hotter the gas, the higher the average kinetic energy

    • The cooler the gas, the lower the average kinetic energy

  • If the gas is heated up, the molecules will travel at a higher speed

    • This means they will collide with the walls more often

    • This creates an increase in pressure

  • Therefore, at a constant volume:

    • an increase in temperature increases the pressure of a gas and vice versa

  • Diagram A shows molecules in the same volume collide with the walls of the container more with an increase in temperature

  • Diagram B shows that the pressure increases steadily as the temperature increases, so the graph is a straight line

Two-part diagram: A shows increased temperature causing gas molecules to move faster and collide more frequently with container walls; B shows a straight-line graph through the origin, with temperature against pressure.
At constant volume, an increase in the temperature of the gas increases the pressure due to more collisions on the container walls

Examiner Tips and Tricks

You are required to be able to describe the link between temperature and pressure qualitatively. This means that the correct use of terms such as 'collision', 'kinetic energy' and 'frequency' will be really important.

Don't forget, this relationship is for gases held at a constant volume!

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Ashika

Author: Ashika

Expertise: Physics Content Creator

Ashika graduated with a first-class Physics degree from Manchester University and, having worked as a software engineer, focused on Physics education, creating engaging content to help students across all levels. Now an experienced GCSE and A Level Physics and Maths tutor, Ashika helps to grow and improve our Physics resources.

Caroline Carroll

Reviewer: Caroline Carroll

Expertise: Head of Content Delivery

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about delivering high-quality resources to help students achieve their full potential.