Thermal Expansion (Cambridge (CIE) IGCSE Physics): Revision Note
Exam code: 0625 & 0972
Thermal expansion
When a material is heated at constant pressure:
Its temperature increases
Its overall volume increases (it expands)
Its density decreases
This expansion happens because:
The particles gain kinetic energy and vibrate or move faster
This increases the average distance between the particles, so the material expands
The expansion comes from an increase in particle separation — the particles themselves do not get any bigger

When a solid is heated, the molecules vibrate more, pushing each other apart
Examiner Tips and Tricks
Remember that it is the material that expands, not the molecules. This trips up many students, losing marks.
As thermal energy is transferred to the material:
The temperature increases
Which increases the kinetic energy of the particles
So the molecules and atoms move or vibrate more quickly
And move further apart
So the separation of the molecules increases and the substance gets bigger
Thermal expansion in terms of particles
Extended tier only
Thermal expansion occurs in solids, liquids and gases
When temperature is increased (at constant pressure):
Solids will tend to expand the least
Gases expand the most
Liquids fall in between the two
This behaviour is influenced by the distances and strength of the forces between particles in each state (opens in a new tab)
State | Magnitude of Expansion | Explanation |
|---|---|---|
Solid | Expands slightly | Strong forces hold the particles in fixed positions, so they can only vibrate a little further apart |
Liquid | Expands more than solids | Weaker forces let the particles move further apart than in a solid, so the expansion is greater |
Gas | Expands significantly | There are almost no forces between the particles, so they move much further apart and the expansion is far greater |
Uses & consequences of thermal expansion
The thermal expansion of materials can have some useful applications as well as some undesirable consequences
Applications of thermal expansion
Useful applications of thermal expansion include:
Liquid-in-glass thermometers
Temperature-activated switches
Liquid-in-glass thermometer
A liquid-in-glass thermometer relies on the expansion of liquids to measure temperature
It consists of a thin glass capillary tube containing a liquid that expands with temperature
At one end of the tube is a glass bulb, containing a large volume of the liquid which expands into the narrow tube when heated
A scale along the side of the tube allows the temperature to be measured based on the length of liquid within the tube
A thermometer is more sensitive if the capillary tube is narrower, because the same expansion of liquid moves further along a narrower tube
Thinner glass around the bulb also makes the thermometer respond more quickly

As the bulb is heated, the liquid expands and moves along the capillary tube
Temperature-activated switches
Temperature-activated switches use a bimetallic strip, made from two different metals joined together
The two metals expand by different amounts when heated, so the strip bends by a predictable amount at a given temperature

The bimetallic strip will bend upwards when heated, closing the circuit
Consequences of thermal expansion
The expansion of solid materials can cause them to buckle if they get too hot
This could include:
Metal railway tracks
Road surfaces
Bridges
Objects that are prone to buckling in this way have gaps built into them, to create space for the expansion to happen without causing damage
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